Chemical Mechanism 8. The mechanism for the reaction described by NO, (g) + CO(g)→ CO,(g) + NO(g) is suggested to be (1) 2 NO,(g) (3)ON + (3)ON NO, (g) + CO,(g) k2 (2) NO, (g) + CO(g) · 3) NO219) +Coa)7 NOg) +cOzeg) The experimental rate law for the production of [CO2] = k1 [NO2]? or d[CO2] . k[NO2]? %3D dt d[NO3] Assuming that [NO3] is governed by a steady state ( = 0 ), is this a valid mechanism? i.e show dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[NO3] , d[Co2] = ? ) dt = ? and that [NO3] and [CO2] are created and destroyed, dt

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8
Chemical Mechanism
8.
The mechanism for the reaction described by
NO, (g) + CO(g) -
→ CO,(g) + NO(g)
is suggested to be
(1) 2 NO,(g) –→ NO,(g) + NO(g)
k2
(2) NO,(g) + CO(g)
- NO, (g) + CO,g)
3) NO219) +Coca) > NOg) + cOz eg)
The experimental rate law for the production of [CO2] = ki [NO2]? or
d[CO2]
k [NO2]?
dt
d[NO3]
Assuming that [NO3] is governed by a steady state (
= 0 ), is this a valid mechanism? i.e show
dt
that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways
d[CO2]
that [NO3] and [CO2] are created and destroyed, INO3]
= ?
dt
and
= ? )
dt
Transcribed Image Text:Chemical Mechanism 8. The mechanism for the reaction described by NO, (g) + CO(g) - → CO,(g) + NO(g) is suggested to be (1) 2 NO,(g) –→ NO,(g) + NO(g) k2 (2) NO,(g) + CO(g) - NO, (g) + CO,g) 3) NO219) +Coca) > NOg) + cOz eg) The experimental rate law for the production of [CO2] = ki [NO2]? or d[CO2] k [NO2]? dt d[NO3] Assuming that [NO3] is governed by a steady state ( = 0 ), is this a valid mechanism? i.e show dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[CO2] that [NO3] and [CO2] are created and destroyed, INO3] = ? dt and = ? ) dt
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