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Chemical Kinetics. The following mechanism has been proposed for the gasphase reaction of chloroform (CHC3) and chlorine: Step 1: Cl, (g) = 2 CI (g) (fast) CI (g) + CHCI, (a) - HCI (g) + CCl,(0) Ci(g) + CCl,(g) - CcI, Step 2: (fast) Step 3: a. What is the overall reaction? b. What are the intermediates in the mechanism? e. What is the molecularity of each of the elementary reactions? (fast)

Chemical Kinetics. The following mechanism has been proposed for the gasphase reaction of chloroform (CHC3) and chlorine: Step 1: Cl, (g) = 2 CI (g) (fast) CI (g) + CHCI, (a) - HCI (g) + CCl,(0) Ci(g) + CCl,(g) - CcI, Step 2: (fast) Step 3: a. What is the overall reaction? b. What are the intermediates in the mechanism? e. What is the molecularity of each of the elementary reactions? (fast)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2. Chemical Kineties. The following mechanism has been proposed for the gasphase reaction of chloroform (CHC3) and chlorine: Cl, (9) = 2 CI (9) CI (g) + CHCI, (a) - HCI (g) + CCl,(0) cig) + CCl,(9) - Cı, Step 1: (fast) Step 2: (fast) Step 3: (fast) a. What is the overall reaction? b. What are the intermediates in the mechanism? c. What is the molecularity of each of the elementary reactions? d. What is the rate-determining step? (e) What is the rate law predicted by this mechanism? (Hint: The overall reaction order is not an integer.)
Transcribed Image Text:2. Chemical Kineties. The following mechanism has been proposed for the gasphase reaction of chloroform (CHC3) and chlorine: Cl, (9) = 2 CI (9) CI (g) + CHCI, (a) - HCI (g) + CCl,(0) cig) + CCl,(9) - Cı, Step 1: (fast) Step 2: (fast) Step 3: (fast) a. What is the overall reaction? b. What are the intermediates in the mechanism? c. What is the molecularity of each of the elementary reactions? d. What is the rate-determining step? (e) What is the rate law predicted by this mechanism? (Hint: The overall reaction order is not an integer.)
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