Chemical Kinetics Tutorials 1. Consider the reaction. 2HB1(g) H2(g) + Brz(g) a. Express the rate of the reaction in terms of the change in concentration of each of the reactants and products. b. In the first 25.0 s of this reaction, the concentration of HBr drops from 0.600 M to 0.512 M. Calculate the average rate of the reaction during this time interval. 2. For the reaction 2A (g) + B(g) 3C(e)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Chemical Kinetics Tutorials
1. Consider the reaction.
2HB1(g)
H2(g) + Brz(g)
a. Express the rate of the reaction in terms of the change in concentration of each of the reactants
and products.
b. In the first 25.0 s of this reaction, the concentration of HBr drops from 0.600 M to 0.512 M.
Calculate the average rate of the reaction during this time interval.
2. For the reaction 2A(g) + B(g) + 3C(g),
a. Determine the expression for the rate of the reaction in terms of the change in concentration of
each of the reactants and products.
3. Consider the tabulated data showing the initial rate of a reaction (A » products) at several
different concentrations of A. What is the order of the reaction? Write a rate law for the reaction
including the value of the rate constant, k.
[A] (M)
Initial Rate (Ms')
0.100
0.053
0.200
0.210
0.300
0.473
4. This reaction is first order in N2O5:
N2O5(g) →NO3(g) + NO2(g)
The rate constant for the reaction at a certain temperature is 0.053s.
a. Calculate the rate of the reaction when [N2O5] = 0.055 M.
b. What is the rate of the reaction at the concentration indicated in part a, if the reaction is second
order? Zero order? (Assume the same numerical value for the rate constant with the appropriate
units.)
5. A reaction in which A, B, and C react to form products is first
order in A, second order in B, and zero order in C.
a. Write a rate law for the reaction.
b.
/hat is the
order of the
c. By what factor does the reaction rate change if [A] is doubled (and the other reactant
concentrations are held constant)?
d. By what factor does the reaction rate change if [B] is doubled (and the other reactant
concentrations are held constant)?
e. By what factor does the reaction rate change if [C] is doubled (and the other reactant
concentrations are held constant)?
Transcribed Image Text:Chemical Kinetics Tutorials 1. Consider the reaction. 2HB1(g) H2(g) + Brz(g) a. Express the rate of the reaction in terms of the change in concentration of each of the reactants and products. b. In the first 25.0 s of this reaction, the concentration of HBr drops from 0.600 M to 0.512 M. Calculate the average rate of the reaction during this time interval. 2. For the reaction 2A(g) + B(g) + 3C(g), a. Determine the expression for the rate of the reaction in terms of the change in concentration of each of the reactants and products. 3. Consider the tabulated data showing the initial rate of a reaction (A » products) at several different concentrations of A. What is the order of the reaction? Write a rate law for the reaction including the value of the rate constant, k. [A] (M) Initial Rate (Ms') 0.100 0.053 0.200 0.210 0.300 0.473 4. This reaction is first order in N2O5: N2O5(g) →NO3(g) + NO2(g) The rate constant for the reaction at a certain temperature is 0.053s. a. Calculate the rate of the reaction when [N2O5] = 0.055 M. b. What is the rate of the reaction at the concentration indicated in part a, if the reaction is second order? Zero order? (Assume the same numerical value for the rate constant with the appropriate units.) 5. A reaction in which A, B, and C react to form products is first order in A, second order in B, and zero order in C. a. Write a rate law for the reaction. b. /hat is the order of the c. By what factor does the reaction rate change if [A] is doubled (and the other reactant concentrations are held constant)? d. By what factor does the reaction rate change if [B] is doubled (and the other reactant concentrations are held constant)? e. By what factor does the reaction rate change if [C] is doubled (and the other reactant concentrations are held constant)?
Expert Solution
steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Reaction Rates
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY