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Carbon dioxide reacts with ammonia to give ammonium carbamate, a solid. The reverse reaction also occurs: CO2(g) + 2 NH3(g) 2NH4OCONH2(s) The forward reaction is first order in CO,g) and second order in NH3(g). Its rate constant is 0.238 atm¯² s-1 at 0.0°C (expressed in terms of partial pressures rather than concentrations). The reaction in the reverse direction is zero order, and its rate constant, at the same temperature, is 1.60 x 10-7 atm s1. Experimental studies show that, at all stages in the progress of this reaction, the net rate is equal to the forward rate minus the reverse rate. Compute the equilibrium constant of this reaction at 0.0°C.

Carbon dioxide reacts with ammonia to give ammonium carbamate, a solid. The reverse reaction also occurs: CO2(g) + 2 NH3(g) 2NH4OCONH2(s) The forward reaction is first order in CO,g) and second order in NH3(g). Its rate constant is 0.238 atm¯² s-1 at 0.0°C (expressed in terms of partial pressures rather than concentrations). The reaction in the reverse direction is zero order, and its rate constant, at the same temperature, is 1.60 x 10-7 atm s1. Experimental studies show that, at all stages in the progress of this reaction, the net rate is equal to the forward rate minus the reverse rate. Compute the equilibrium constant of this reaction at 0.0°C.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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Carbon dioxide reacts with ammonia to give ammonium carbamate, a solid. The reverse reaction also occurs: CO2(g) + 2 NH3(g) 2NH4OCONH2(s) The forward reaction is first order in CO,g) and second order in NH3(g). Its rate constant is 0.238 atm¯² s-1 at 0.0°C (expressed in terms of partial pressures rather than concentrations). The reaction in the reverse direction is zero order, and its rate constant, at the same temperature, is 1.60 x 10-7 atm s1. Experimental studies show that, at all stages in the progress of this reaction, the net rate is equal to the forward rate minus the reverse rate. Compute the equilibrium constant of this reaction at 0.0°C.
Transcribed Image Text:Carbon dioxide reacts with ammonia to give ammonium carbamate, a solid. The reverse reaction also occurs: CO2(g) + 2 NH3(g) 2NH4OCONH2(s) The forward reaction is first order in CO,g) and second order in NH3(g). Its rate constant is 0.238 atm¯² s-1 at 0.0°C (expressed in terms of partial pressures rather than concentrations). The reaction in the reverse direction is zero order, and its rate constant, at the same temperature, is 1.60 x 10-7 atm s1. Experimental studies show that, at all stages in the progress of this reaction, the net rate is equal to the forward rate minus the reverse rate. Compute the equilibrium constant of this reaction at 0.0°C.
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