Homework Help is Here – Start Your Trial Now!
Science
Chemistry
Can the following two molecules be seperated by column chromatography or recrystalization? Explain

Can the following two molecules be seperated by column chromatography or recrystalization? Explain

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question

Can the following two molecules be seperated by column chromatography or recrystalization? Explain 

### Cyclohexane Chair Conformations with Bromine Substitution On this page, we examine the structural representations of cyclohexane in its chair conformation, focusing on the impact of substituting a hydrogen atom with a bromine atom (Br). The chair conformation is the most stable form of cyclohexane due to minimized steric strain. #### Structures: 1. **Left Diagram: Cyclohexane with Equatorial Bromine Substitution** - This diagram shows a cyclohexane molecule in a chair conformation. - A bromine atom (Br) is attached to one of the carbon atoms. - The bromine atom is positioned equatorially, meaning it is aligned roughly parallel to the plane of the ring. This positioning minimizes steric hindrance with other substituents and is typically more stable compared to axial positions. 2. **Right Diagram: Cyclohexane with Axial Bromine Substitution** - Here, the cyclohexane molecule is also depicted in a chair conformation. - However, the bromine atom (Br) is attached in an axial position. - The axial position places the bromine atom perpendicular to the plane of the ring, which might introduce more steric hindrance compared to the equatorial position. ### Key Concepts: - **Chair Conformation:** - A three-dimensional shape that cyclohexane adopts to relieve angle strain and torsional strain, resembling a chair. - Chair conformations are typically interconvertible through a process known as ring flipping. - **Equatorial Position:** - Atoms or groups are positioned around the equator of the cyclohexane ring. - Generally more stable due to reduced steric interactions. - **Axial Position:** - Atoms or groups extend perpendicular to the ring, alternating positions above and below the plane. - Less stable due to increased steric hindrance from 1,3-diaxial interactions. Understanding the difference in stability between axial and equatorial positions is essential in predicting the behavior of substituted cyclohexane in chemical reactions. These diagrams illustrate the two possible positions for substituents and highlight the importance of conformational analysis in organic chemistry.
Transcribed Image Text:### Cyclohexane Chair Conformations with Bromine Substitution On this page, we examine the structural representations of cyclohexane in its chair conformation, focusing on the impact of substituting a hydrogen atom with a bromine atom (Br). The chair conformation is the most stable form of cyclohexane due to minimized steric strain. #### Structures: 1. **Left Diagram: Cyclohexane with Equatorial Bromine Substitution** - This diagram shows a cyclohexane molecule in a chair conformation. - A bromine atom (Br) is attached to one of the carbon atoms. - The bromine atom is positioned equatorially, meaning it is aligned roughly parallel to the plane of the ring. This positioning minimizes steric hindrance with other substituents and is typically more stable compared to axial positions. 2. **Right Diagram: Cyclohexane with Axial Bromine Substitution** - Here, the cyclohexane molecule is also depicted in a chair conformation. - However, the bromine atom (Br) is attached in an axial position. - The axial position places the bromine atom perpendicular to the plane of the ring, which might introduce more steric hindrance compared to the equatorial position. ### Key Concepts: - **Chair Conformation:** - A three-dimensional shape that cyclohexane adopts to relieve angle strain and torsional strain, resembling a chair. - Chair conformations are typically interconvertible through a process known as ring flipping. - **Equatorial Position:** - Atoms or groups are positioned around the equator of the cyclohexane ring. - Generally more stable due to reduced steric interactions. - **Axial Position:** - Atoms or groups extend perpendicular to the ring, alternating positions above and below the plane. - Less stable due to increased steric hindrance from 1,3-diaxial interactions. Understanding the difference in stability between axial and equatorial positions is essential in predicting the behavior of substituted cyclohexane in chemical reactions. These diagrams illustrate the two possible positions for substituents and highlight the importance of conformational analysis in organic chemistry.
Expert Solution
steps

Step by step

Solved in 2 steps

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Analytical Separations
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS