Can someone please help me with both charts. Do not understand at all. Please explain how you get the frequency and functional group aand chemical shift. I need all work shown to fully understand thank you!

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Can someone please help me with both charts. Do not understand at all. Please explain how you get the frequency and functional group aand chemical shift. I need all work shown to fully understand thank you!

### Educational Content: Understanding NMR Spectroscopy

#### Molecular Formula
- **MF:** C₆H₁₂O₂

#### NMR Spectrum Interpretation

###### 1H NMR Spectrum

The provided NMR spectrum displays signals that represent different hydrogen environments in the molecule. The x-axis represents the chemical shift in parts per million (PPM).

- **Peak at ~4.0 PPM:** This peak is designated as 3H, indicating 3 hydrogen atoms contributing to this signal.
  
- **Peak at ~2.5 PPM:** Labeled as 1H, suggesting that 1 hydrogen atom is present in this chemical environment.
  
- **Peak at ~2.0 PPM:** This peak has 2H, associated with 2 hydrogen atoms.
  
- **Peak at ~1.0 PPM:** Labeled as 6H, indicating 6 hydrogens are present.

The relative intensities of these peaks provide insights into the symmetry and chemical environment within the molecule.

---

#### Data Tables for Further Analysis

**IR (Infrared Spectroscopy) Table**
- **Frequency:** [Leave Blank]
- **Functional Group:** [Leave Blank]

**13C NMR Table**
- **Chemical Shift:** [Leave Blank]
- **Type of Bonding Environment:** [Leave Blank]

This template allows for the systematic identification of functional groups and chemical environments, essential for confirming the structure of the compound.

#### Conclusion

The NMR data provides valuable insights into the structure of the molecule C₆H₁₂O₂. Understanding each peak and its corresponding hydrogen atoms is crucial for complete molecule characterization.

---

This analysis provides a foundational understanding of how to read and interpret NMR spectra, critical skills in organic chemistry for determining molecular structures.
Transcribed Image Text:### Educational Content: Understanding NMR Spectroscopy #### Molecular Formula - **MF:** C₆H₁₂O₂ #### NMR Spectrum Interpretation ###### 1H NMR Spectrum The provided NMR spectrum displays signals that represent different hydrogen environments in the molecule. The x-axis represents the chemical shift in parts per million (PPM). - **Peak at ~4.0 PPM:** This peak is designated as 3H, indicating 3 hydrogen atoms contributing to this signal. - **Peak at ~2.5 PPM:** Labeled as 1H, suggesting that 1 hydrogen atom is present in this chemical environment. - **Peak at ~2.0 PPM:** This peak has 2H, associated with 2 hydrogen atoms. - **Peak at ~1.0 PPM:** Labeled as 6H, indicating 6 hydrogens are present. The relative intensities of these peaks provide insights into the symmetry and chemical environment within the molecule. --- #### Data Tables for Further Analysis **IR (Infrared Spectroscopy) Table** - **Frequency:** [Leave Blank] - **Functional Group:** [Leave Blank] **13C NMR Table** - **Chemical Shift:** [Leave Blank] - **Type of Bonding Environment:** [Leave Blank] This template allows for the systematic identification of functional groups and chemical environments, essential for confirming the structure of the compound. #### Conclusion The NMR data provides valuable insights into the structure of the molecule C₆H₁₂O₂. Understanding each peak and its corresponding hydrogen atoms is crucial for complete molecule characterization. --- This analysis provides a foundational understanding of how to read and interpret NMR spectra, critical skills in organic chemistry for determining molecular structures.
**Combined Spectral Problems: IR, ¹³C & ¹H**

*All spectra are either from SDBS (Japan National Institute of Advanced Industrial Science and Technology) or simulated.*

**Task:** 
Propose structures for the following problems. Use the tables on the following pages to show your work.

---

**C. Compound: C₆H₁₂O₂**

### Infrared (IR) Spectrum:
- The IR spectrum displays various peaks indicating different functional groups present in the molecule. The specific absorption bands should be analyzed to deduce functional groups like alcohols, carbonyls, etc. 

### Carbon-13 Nuclear Magnetic Resonance (¹³C NMR) Spectrum:
- The ¹³C NMR spectrum shows peaks at specific ppm values, indicating the chemical environment of the carbon atoms in the compound. The peaks' positions help identify different types of carbon atoms (e.g., alkane, alkene, carbonyl).

### Proton Nuclear Magnetic Resonance (¹H NMR) Spectrum:
- The scan is incomplete here, but would typically provide information about the hydrogen atoms' environment in the molecule, including signal multiplicity indicating neighboring hydrogen interactions.

**Graph Analyses:**
1. **IR Spectrum:**
   - The graph shows transmittance against wave numbers (cm⁻¹). The dips in the spectrum represent absorption peaks. Key peaks should be correlated with common functional groups.

2. **¹³C NMR Spectrum:**
   - The graph displays chemical shift values from 0 to 200 ppm. Peaks represent the different carbon environments in the molecule. The number of distinct peaks indicates the number of unique carbon environments.

By analyzing these spectra, you can propose a possible structure for the compound C₆H₁₂O₂. Consider the functional groups suggested by the IR spectrum and the carbon environment given by the ¹³C NMR data.
Transcribed Image Text:**Combined Spectral Problems: IR, ¹³C & ¹H** *All spectra are either from SDBS (Japan National Institute of Advanced Industrial Science and Technology) or simulated.* **Task:** Propose structures for the following problems. Use the tables on the following pages to show your work. --- **C. Compound: C₆H₁₂O₂** ### Infrared (IR) Spectrum: - The IR spectrum displays various peaks indicating different functional groups present in the molecule. The specific absorption bands should be analyzed to deduce functional groups like alcohols, carbonyls, etc. ### Carbon-13 Nuclear Magnetic Resonance (¹³C NMR) Spectrum: - The ¹³C NMR spectrum shows peaks at specific ppm values, indicating the chemical environment of the carbon atoms in the compound. The peaks' positions help identify different types of carbon atoms (e.g., alkane, alkene, carbonyl). ### Proton Nuclear Magnetic Resonance (¹H NMR) Spectrum: - The scan is incomplete here, but would typically provide information about the hydrogen atoms' environment in the molecule, including signal multiplicity indicating neighboring hydrogen interactions. **Graph Analyses:** 1. **IR Spectrum:** - The graph shows transmittance against wave numbers (cm⁻¹). The dips in the spectrum represent absorption peaks. Key peaks should be correlated with common functional groups. 2. **¹³C NMR Spectrum:** - The graph displays chemical shift values from 0 to 200 ppm. Peaks represent the different carbon environments in the molecule. The number of distinct peaks indicates the number of unique carbon environments. By analyzing these spectra, you can propose a possible structure for the compound C₆H₁₂O₂. Consider the functional groups suggested by the IR spectrum and the carbon environment given by the ¹³C NMR data.
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