Can carbon be used to reduce zinc oxide to zinc at a) 1000 K and b) 1500 K? The reaction we require is: 2C + 2ZNO, = 2Zn + 2CO

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Ellingham Diagram
1. Can carbon be used to reduce zinc oxide to zinc at
a) 1000 K and b) 1500 K?
The reaction we require is: 2C + 2ZnO, = 2Zn + 2CO
2. What is the best reducing agent at all temperatures up to 2000°C?
3. Write the chemical equations corresponding to the lines ending with
Al,0, and ZnO. Show how they can be combined to give a
spontaneous reaction between one of these metals and the oxide of the
other.
4. Why is gold not found in nature as its oxide?
5. Will Al powder react with Cr,O;? If so at what temperature? Write
balance equation.
Transcribed Image Text:Ellingham Diagram 1. Can carbon be used to reduce zinc oxide to zinc at a) 1000 K and b) 1500 K? The reaction we require is: 2C + 2ZnO, = 2Zn + 2CO 2. What is the best reducing agent at all temperatures up to 2000°C? 3. Write the chemical equations corresponding to the lines ending with Al,0, and ZnO. Show how they can be combined to give a spontaneous reaction between one of these metals and the oxide of the other. 4. Why is gold not found in nature as its oxide? 5. Will Al powder react with Cr,O;? If so at what temperature? Write balance equation.
Ellingham Diagrams
0°C
200
400
600
800
1000
1200
1400
1600
2000*C atm.
ie00
বি
Hi00
10
200
k00
10
2Ni+ Oz2NO
zco
300
ర
300
10
C+0g co
400
100
2co
500
WOS
500
10-
2 +0 2M0
600
I05
-
10
Si+ s
700
700
10
of
800
800
900
900 10- 1O
Line
code
Element or
lower oalde
Oside
HH000 10
2800
Condensed
Condensed
-----m
Goseous
Condensed
Goseous
Zro
Condensed
Goseous
Goseous
25r0
10-
Suggested ccuracies
Changes of
O I kilocelorie
O 1 3 kilocalories
O : IONilecalories
O 1>1Olocaleries
state
Melting pt
Boiling p
10
1200
Sublimation pt
Logo
Tronsition pt.
1200
OK
200
400
600
800
1000
1200
1400
1600
1800
2000
Temperature
E 1040
-30
10
1034
1032
1030
8, -
10"
Standard free energies of formation of oxides (-AG= -RT Inpo, ): kilojoules/mole 02
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Transcribed Image Text:Ellingham Diagrams 0°C 200 400 600 800 1000 1200 1400 1600 2000*C atm. ie00 বি Hi00 10 200 k00 10 2Ni+ Oz2NO zco 300 ర 300 10 C+0g co 400 100 2co 500 WOS 500 10- 2 +0 2M0 600 I05 - 10 Si+ s 700 700 10 of 800 800 900 900 10- 1O Line code Element or lower oalde Oside HH000 10 2800 Condensed Condensed -----m Goseous Condensed Goseous Zro Condensed Goseous Goseous 25r0 10- Suggested ccuracies Changes of O I kilocelorie O 1 3 kilocalories O : IONilecalories O 1>1Olocaleries state Melting pt Boiling p 10 1200 Sublimation pt Logo Tronsition pt. 1200 OK 200 400 600 800 1000 1200 1400 1600 1800 2000 Temperature E 1040 -30 10 1034 1032 1030 8, - 10" Standard free energies of formation of oxides (-AG= -RT Inpo, ): kilojoules/mole 02 国可回日
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