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Calculate Z and V (in cm3·gmol-1) for isopropanol vapor at 200°C and 10 atm by the following method: (a) Use the truncated virial equations. В V =1+ V'y² C with the experimentally determined V² virial coefficients

Calculate Z and V (in cm3·gmol-1) for isopropanol vapor at 200°C and 10 atm by the following method: (a) Use the truncated virial equations. В V =1+ V'y² C with the experimentally determined V² virial coefficients

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Topic Real Gases and Equations of States

 

4. Calculate Z and V (in cm3-gmol-1) for isopropanol vapor at 200°C and 10 atm by the following method: (a) Use the truncated virial equations. В V = 1+ V C with the experimentally determined V? virial coefficients B = -388 cm3 gmol-1 C = - 26000 cm6-gmol-2
Transcribed Image Text:4. Calculate Z and V (in cm3-gmol-1) for isopropanol vapor at 200°C and 10 atm by the following method: (a) Use the truncated virial equations. В V = 1+ V C with the experimentally determined V? virial coefficients B = -388 cm3 gmol-1 C = - 26000 cm6-gmol-2
ВР (b) Use the truncated virial equations: V =1+ RT employing the generalized correlation to estimate B. (c) Use the Van der Waals equation: V Z = V -b RTV a 9 employing a =-RTV. 8. V b 3 to calculate a and b. The following physical constants are available for isopropanol T = 508.2 K V. = 220 cm3 gmol-1 P. = 50 atm @ = 0.7 %3D
Transcribed Image Text:ВР (b) Use the truncated virial equations: V =1+ RT employing the generalized correlation to estimate B. (c) Use the Van der Waals equation: V Z = V -b RTV a 9 employing a =-RTV. 8. V b 3 to calculate a and b. The following physical constants are available for isopropanol T = 508.2 K V. = 220 cm3 gmol-1 P. = 50 atm @ = 0.7 %3D
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