Calculate the Redlich-Kwong parameters of fluorine from the values of the critical constants and compare your results with the values for a and b in Table 4 of Chapter 7.
Calculate the Redlich-Kwong parameters of fluorine from the values of the critical constants and compare your results with the values for a and b in Table 4 of Chapter 7.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Calculate the Redlich-Kwong parameters of fluorine from the values of the critical constants and compare your results with the values for a and b in Table 4 of Chapter 7.
Transcribed Image Text:40
Table 7.4 vdW & RK Parameters for Selected Gases
TABLE 7.4 VAN DER WAALS AND REDLICH-KWONG PARAMETERS FOR SELECTED GASES
van der Waals
Redlich–Kwong
Substance
Formula
a (dm“ bar mol-)
b (dm² mol¯')
a (dm“ bar mol-2K/?)
b (dm² mol-')
Ammonia
NH3
4.225
0.0371
86.12
0.02572
Argon
1.355
0.0320
16.86
0.02219
Ar
Benzene
CH6
18.82
0.1193
452.0
0.08271
Bromine
Brz
CO2
Co
9.75
0.0591
236.5
0.04085
Carbon dioxide
3.658
0.0429
64.63
0.02971
Carbon monoxide
1.472
0.0395
17.20
0.02739
Ethane
5.580
0.0651
98.79
0.04514
Ethanol
C;H,OH
12.56
0.0871
287.7
0.06021
Ethene
C-H.
4.612
0.0582
78.51
0.04034
Ethyne
C;H;
4.533
0.05240
80.65
0.03632
Fluorine
F2
1.171
0.0290
14.17
0.01993
Hydrogen
H2
0.2452
0.0265
1.427
0.01837
Methane
CH.
2.303
0.0431
32.20
0.02985
Methanol
CH;OH
9.476
0.0659
217.1
0.04561
Nitrogen
N2
1.370
0.0387
15.55
0.02675
Oxygen
1.382
0.0319
17.40
0.02208
Pentane
C3H12
19.09
0.1448
419.2
0.1004
Propane
9.39
0.0905
182.9
0.06271
Pyridine
C,H;N
19.77
0.1137
498.8
0.07877
Tetrachloromethane
CC4
20.01
0.1281
473.2
0.08793
Water
H;O
5.537
0.0305
142.6
0.02113
Xenon
Xe
4.192
0.0516
72.30
0.03574
Source: Calculated from critical constants.
O 2010 Pearson Education, Inc.
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