Calculate the purely theoretical lambda_max in nm for each dye in the simplest particle-in-a-box model (the Kuhn Model) by using the following equation: lambda = 63.7((P+3)^2/(P+4)) (in nm); where p is the number of carbon atoms in a polymethine chain. Dye 1: 1,1'- diethyl-2,2'-cyanine iodide Dye 2: 1,1'- diethyl- 2,2' -carbocyanine iodide (Pinacyanol) Dye 3: 1,1'- diethyl- 2,2' -dicarbocyanine iodide For the three wavelengths calculate and tabulate the wavenumber (cm^-1) and excitation energy (kJ/mol) for each

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.37P
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Calculate the purely theoretical lambda_max in nm for each dye in the simplest particle-in-a-box model (the Kuhn Model) by using the following equation: lambda = 63.7((P+3)^2/(P+4)) (in nm); where p is the number of carbon atoms in a polymethine chain.

Dye 1: 1,1'- diethyl-2,2'-cyanine iodide

Dye 2: 1,1'- diethyl- 2,2' -carbocyanine iodide (Pinacyanol)

Dye 3: 1,1'- diethyl- 2,2' -dicarbocyanine iodide

For the three wavelengths calculate and tabulate the wavenumber (cm^-1) and excitation energy (kJ/mol) for each

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