Calculate the pH when 50.0 mL of 0.150 M KOH is mixed with 20.0 mL of 0.300 M HBRO (Ka = 2.5 × 10-º)

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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**Calculate the pH of a Mixture of KOH and HBrO**

**Problem Statement:**

Determine the pH when 50.0 mL of 0.150 M KOH is mixed with 20.0 mL of 0.300 M HBrO. The acid dissociation constant (Ka) for HBrO is 2.5 × 10⁻⁹.

**Approach:**

1. **Calculate moles of KOH and HBrO:**

   - Moles of KOH = Volume (L) × Molarity 
   - Moles of HBrO = Volume (L) × Molarity 

2. **Determine the limiting reactant:**  
   Determine which reactant is in excess and which is the limiting reactant.

3. **Calculate the concentration of the remaining species:**
   - Calculate the concentration of the resultant solution formed after the neutralization reaction.

4. **Use the Henderson-Hasselbalch equation if applicable:**
   - If a buffer solution is formed, the Henderson-Hasselbalch equation can be used to find the pH.

5. **Calculate the pH:**
   - Based on the dominant species present, calculate the pH.

This problem involves concepts of acid-base neutralization and may require the application of equilibrium principles if a buffer system is established.
Transcribed Image Text:**Calculate the pH of a Mixture of KOH and HBrO** **Problem Statement:** Determine the pH when 50.0 mL of 0.150 M KOH is mixed with 20.0 mL of 0.300 M HBrO. The acid dissociation constant (Ka) for HBrO is 2.5 × 10⁻⁹. **Approach:** 1. **Calculate moles of KOH and HBrO:** - Moles of KOH = Volume (L) × Molarity - Moles of HBrO = Volume (L) × Molarity 2. **Determine the limiting reactant:** Determine which reactant is in excess and which is the limiting reactant. 3. **Calculate the concentration of the remaining species:** - Calculate the concentration of the resultant solution formed after the neutralization reaction. 4. **Use the Henderson-Hasselbalch equation if applicable:** - If a buffer solution is formed, the Henderson-Hasselbalch equation can be used to find the pH. 5. **Calculate the pH:** - Based on the dominant species present, calculate the pH. This problem involves concepts of acid-base neutralization and may require the application of equilibrium principles if a buffer system is established.
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