Calculate the lattice energy for CsCl using a Born-Haber cycle. Also calculate the approximate lattice energy using the Kapustinskii and Born-Landé equations and compare those two results to the value from the Born-Haber cycle. Use the textbook appendices to find the values needed for the calculations. Not in appendices: For Cs, AHvap = 64.0 kJ/mol; IE = 375.7 kJ/mol %3D
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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