Calculate the G°rxn using the following information. 2 HNO3(aq) +NO(g) → 3 NO2(g) + H2O(l) AG'rxn =? AH°f (kJ/mol) -207.0 91.3 33.2 -285.8 SJ/mol K 146.0 210.8 240.1 70.0 -151 kJ -85.5 kJ +50.8 kJ +222 kJ -186 kJ

Calculate the G°rxn using the following information. 2 HNO3(aq) +NO(g) → 3 NO2(g) + H2O(l) AG'rxn =? AH°f (kJ/mol) -207.0 91.3 33.2 -285.8 SJ/mol K 146.0 210.8 240.1 70.0 -151 kJ -85.5 kJ +50.8 kJ +222 kJ -186 kJ

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter6: Thermochemistry

Section: Chapter Questions

Problem 128CWP: Calculate H for the reaction N2H4(l)+O2(g)N2(g)+2H2O(l) given the following data: Equation H(KJ)...

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Thermodynamics provides a way to interpret everyday occurrences. If you live in northern climates, one common experience is that during early winter, snow falls but then melts when it hits the ground. Both the formation and the melting happen spontaneously. How can thermodynamics explain both of these seemingly opposed events?
Given the following data 2O3(g) 3O2(g)H = 427 kJ O2(g) 2O(g)H = 495 kJ NO(g) + O3(g) NO2(g) + O2(g)H = 199 kJ Calculate H for the reaction NO(g) + O(g) NO2(g)
9.83 A student performing a calorimetry experiment combined 100.0 mL of 0.50 M HCl and 100.0 mL of 0.50 M NaOH in a coffee cup calorimeter. Both solutions were initially at 20.0°C, but when the two were mixed, the temperature rose to 23.2°C. (a) Suppose the experiment is repeated in the same calorimeter but this time using 200 mL of 0.50 M HCl and 200.0 mL of 0.50 M NaOH. Will the T observed he greater than, less than, or equal to that in the first experiment, and why? (b) Suppose that the experiment is repeated once again in the same calorimeter, this time using 100 mL of 1.00 M HCl and 100.0 mL of 1.00 M NaOH. Will the T observed he greater than, less than, or equal to that in the first experiment, and why?
Coal is used as a fuel in some electric-generating plants. Coal is a complex material, but for simplicity we may consider it to be a form of carbon. The energy that can be derived from a fuel is sometimes compared with the enthalpy of the combustion reaction: C(s)+O2(g)CO2(g) Calculate the standard enthalpy change for this reaction at 25C. Actually, only a fraction of the heat from this reaction is available to produce electric energy. In electric generating plants, this reaction is used to generate heat for a steam engine, which turns the generator. Basically the steam engine is a type of heat engine in which steam enters the engine at high temperature (Th), work is done, and the steam then exits at a lower temperature (Tl). The maximum fraction, f, of heat available to produce useful energy depends on the difference between these temperatures (expressed in kelvins), f = (Th Tl)/Th. What is the maximum heat energy available for useful work from the combustion of 1.00 mol of C(s) to CO2(g)? (Assume the value of H calculated at 25C for the heat obtained in the generator.) It is possible to consider more efficient ways to obtain useful energy from a fuel. For example, methane can be burned in a fuel cell to generate electricity directly. The maximum useful energy obtained in these cases is the maximum work, which equals the free-energy change. Calculate the standard free-energy change for the combustion of 1.00 mol of C(s) to CO2(g). Compare this value with the maximum obtained with the heat engine described here.
Shown below is a diagram depicting the enthalpy change of a chemical reaction run at constant pressure. a Is the reaction exothermic or endothermic? b What is the sign of H? c What is the sign of q? d If the reaction does no work, what is the sign of E for this process?
Which of the following processes will lead to a decrease in the internal energy of a system? (1) Energy is transferred as heat to the system; (2) energy is transferred as heat from the system; (3) energy is transferred as work done on the system; or (4) energy is transferred as work done by the system. (a) 1 and 3 (b) 2 and 4 (c) 1 and 4 (d) 2and3
For the reaction TiCl2(s) + Cl2(g) TiCl4(), rG = 272.8 kj/mol-txn. Using this value and other data available in Appendix L, calculate the value of fG for TiCl2(s).
Calculate H for each of the following reactions using the data in Appendix 4: 4Na(s)+O2(g)2Na2O(s)2Na(s)+2H2O(l)2NaOH(aq)+H2(g)2Na(s)+CO2(g)Na2O(s)+CO(g) Explain why a water or carbon dioxide fire extinguisher might not be effective in putting out a sodium fire.
Alloys When a 58.8-g piece of hot alloy is placed in125 g of cold water in a calorimeter, the temperature ofthe alloy decreases by 106.1°C, while the temperature ofthe water increases by 10.5°C. What is the specific heat ofthe alloy?
9.38 The energy densities of various types of coal are listed below: Anthracite 35 kJ/g Subbituminous 31 kJ/g Bituminous 28 kJ/g Lignite 26 kJ/g An unknown sample of one of these coals is burned in an apparatus with a calorimeter constant of 1.3 kJ/°C. When a 0.367-g sample is used, the temperature change is 8.75°C. Which type of coal is the sample?
The bombardier beetle uses an explosive discharge as a defensive measure. The chemical reaction involved is the oxidation of hydroquinone by hydrogen peroxide to produce quinone and water: C6H4(OH)2(aq) + H2O2(aq) C6H4O2(aq) + 2H2O(l) Calculate H for this reaction from the following data: C6H4(OH)2(aq) C6H4O2(aq) + H2(g)H = 177.4 kJ H2(g) + O2(g) H2O2(aq)H = 191.2 kJ H2(g) + 12O2(g) H2O(g)H = 241.8 kJ H2O(g) H2O(l)H = 43.8 kJ
9.20 State the first law of thermodynamics briefly in your own words.