Calculate the equilibrium partial pressure of PCI3 in a 3.00-L vessel that was charged with 0.123 atm of PCI5. PCI5(g) = PCI3(g) + Cl2(g) (Keg = 0.0121)

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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**Problem Statement:**
Calculate the equilibrium partial pressure of PCl₃ in a 3.00-L vessel that was charged with 0.123 atm of PCl₅.

**Reaction:**
\[ \text{PCl}_5(g) \rightleftharpoons \text{PCl}_3(g) + \text{Cl}_2(g) \]

**Equilibrium Constant:**
\[ K_{eq} = 0.0121 \]

**Answer Options:**
- 0.0900 atm
- 0.0386 atm
- 0.0110 atm
- 0.0330 atm (selected option)
- 0.123 atm

**Explanation:**
The problem involves calculating the equilibrium partial pressure of phosphorus trichloride (PCl₃) in a closed system at equilibrium, given the initial conditions and the equilibrium constant. The selected answer is 0.0330 atm, indicating the equilibrium pressure of PCl₃.
Transcribed Image Text:**Problem Statement:** Calculate the equilibrium partial pressure of PCl₃ in a 3.00-L vessel that was charged with 0.123 atm of PCl₅. **Reaction:** \[ \text{PCl}_5(g) \rightleftharpoons \text{PCl}_3(g) + \text{Cl}_2(g) \] **Equilibrium Constant:** \[ K_{eq} = 0.0121 \] **Answer Options:** - 0.0900 atm - 0.0386 atm - 0.0110 atm - 0.0330 atm (selected option) - 0.123 atm **Explanation:** The problem involves calculating the equilibrium partial pressure of phosphorus trichloride (PCl₃) in a closed system at equilibrium, given the initial conditions and the equilibrium constant. The selected answer is 0.0330 atm, indicating the equilibrium pressure of PCl₃.
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