Calculate the equilibrium constant, Kc, of the reaction:  HCO3-(aq) + HCO3-(aq) ↔ H2CO3(aq) + CO32- , Kc = ?  Based on your result, do you expect this reaction to occur in the left-to-right direction?

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Calculate the equilibrium constant, Kc, of the reaction: 

HCO3-(aq)  +  HCO3-(aq)  ↔  H2CO3(aq)  +  CO32- , Kc = ? 

Based on your result, do you expect this reaction to occur in the left-to-right direction? 

Complete the Kai expression for H₂CO3 in an aqueous solution.
Kal
=
4.45 × 10-7
=
[H3O+]
[HCO3]
[H₂CO3]
Transcribed Image Text:Complete the Kai expression for H₂CO3 in an aqueous solution. Kal = 4.45 × 10-7 = [H3O+] [HCO3] [H₂CO3]
Complete the K₁2 expression for H₂CO3 in an aqueous solution.
Ka2 = 4.69 × 10-11
=
[CO-]
[HCO3]
[H3O+]
Transcribed Image Text:Complete the K₁2 expression for H₂CO3 in an aqueous solution. Ka2 = 4.69 × 10-11 = [CO-] [HCO3] [H3O+]
Expert Solution
Step 1: Given information:

An equilibrium chemical reaction is given as follows:

H C O subscript 3 to the power of minus space left parenthesis a q right parenthesis space plus space H C O subscript 3 to the power of minus space left parenthesis a q right parenthesis space left right arrow space H subscript 2 C O subscript 3 space left parenthesis a q right parenthesis space plus space C O subscript 3 to the power of 2 minus end exponent space left parenthesis a q right parenthesis ...(i)

The equilibrium constant can be defined as the ratio of the product of the equilibrium molar concentrations of products and the product of the equilibrium molar concentrations of reactants, with the each concentration term raised to an exponent equal to the stoichiometric coefficient.

We have to determine the equilibrium constant, Kc for the above equilibrium.

The first acid dissociation constant, Ka1 for H2CO3 is given as 4.45 space cross times space 10 to the power of negative 7 end exponent.

The second acid dissociation constant, Ka2 for H2CO3 is given as 4.69 space cross times space 10 to the power of negative 11 end exponent.

H2COis a weak diprotic acid and its dissociation takes place in two steps.

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