Calcium in a sample solution is determined by atomic absorption spectroscopy (AAS). A stock solution of calcium is prepared by dissolving 1.834 g CaCl, 2H,O in water and diluting to 1 litre. From this stock solution, the second stock solution is prepared by the dilution factor of 10. Three standard solutions of calcium are prepared from the second stock solution with the following dilution factor: 20 (first standard solution), 10 (second standard solution) and 5 (third standard solution). A blank solution is prepared as well. Absorbance signals of AAS are as follows: 1.5 (blank solution), 10.6 (first standard solution), 20.1 (second standard solution), 38.5 (third standard solution), 29.6 (sample solution). (Molar mass; Ca 40.00 g mol-1, CI = 35.45 g mol-, o 16.00 g mol-, H = 1.00 g mol-) a. Construct ONE (1) plot that could be used to represent the calibration curve. b. From the plot of Q1a, determine the amount of calcium in parts per million.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter15: Acid–base Equilibria
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1. Calcium in a sample solution is determined by atomic absorption
spectroscopy (AAS). A stock solution of calcium is prepared by dissolving
1.834 g CaCl, 2H,0 in water and diluting to 1 litre. From this stock solution,
the second stock solution is prepared by the dilution factor of 10. Three
standard solutions of calcium are prepared from the second stock solution
with the following dilution factor: 20 (first standard solution), 10 (second
standard solution) and 5 (third standard solution). A blank solution is
prepared as well. Absorbance signals of AAS are as follows: 1.5 (blank
solution), 10.6 (first standard solution), 20.1 (second standard solution), 38.5
(third standard solution), 29.6 (sample solution).
(Molar mass; Ca = 40.00 g mol-, CI = 35.45 g mol-, 0 = 16.00 g mol-',
H = 1.00 g mol-1)
a.
Construct ONE (1) plot that could be used to represent the calibration
curve.
b.
From the plot of Q1a, determine the amount of calcium in parts per
million.
Transcribed Image Text:1. Calcium in a sample solution is determined by atomic absorption spectroscopy (AAS). A stock solution of calcium is prepared by dissolving 1.834 g CaCl, 2H,0 in water and diluting to 1 litre. From this stock solution, the second stock solution is prepared by the dilution factor of 10. Three standard solutions of calcium are prepared from the second stock solution with the following dilution factor: 20 (first standard solution), 10 (second standard solution) and 5 (third standard solution). A blank solution is prepared as well. Absorbance signals of AAS are as follows: 1.5 (blank solution), 10.6 (first standard solution), 20.1 (second standard solution), 38.5 (third standard solution), 29.6 (sample solution). (Molar mass; Ca = 40.00 g mol-, CI = 35.45 g mol-, 0 = 16.00 g mol-', H = 1.00 g mol-1) a. Construct ONE (1) plot that could be used to represent the calibration curve. b. From the plot of Q1a, determine the amount of calcium in parts per million.
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