Can you answer this questions regarding the IR absorbtion LODTABLE 18.2Characteristic infrared absorption peaks of functional groupsVibrationPosition (cm-')IntensityCommentAlkanesC-H stretchC-H bend2962-2853m to s1470-1430 and 1375–1365m to wAlkenes=C--H stretch 3100–3010C=C stretchC-H bend1680–1640 (sat.), 1630–1590 (conj.)995-685w to mSee Table 18.3 for detail.Alkynes=C-H stretch 3300-320050C=C stretch2250-2100m to wAromaticC–H stretch3080-3020m to wC=C stretchC-H bend1650–1580m to w900-680See Table 18.3 for detail.Alcohols0-H stretch3650–3550Free3550-3300br, sHydrogen bondedC-O stretch1260–1000AminesN-H stretch3500-3100br, m1° (two bands), 2° (one band)4D003000200015001000500NitrilesHAVENUMB ERI -|lCEN stretch2280–2200AldehydesC-H stretchC=O stretch2900-2820 and 2775-2700H-C=01740–1720 (sat.), 1705-1680 (conj.)KetonesC=0 stretch1725–1705 (sat.), 1685–1665 (conj.)Esters`HC=0 stretchВ1750–1735 (sat.), 1730–1715 (conj.)AH,COCH,CH,C-O stretch1250–1160H,C-oAcidsEthyl acetate0-H stretchC=0 stretch3500–25001725–1700 (sat.), 1715–1680 (conj.)}p-AnisaldehydeAmidesN-H stretch3500–31501° (two bands), 2° (one band)mC=0 stretch1680–1630AnhydridesC=O stretch(-O stretch1850–1800 and 1790–17401050-900`CHОНAcid chloridesC=0 stretch1820–1770DNitroNO, stretch1660–1490 and 1390–1260Benzoic acida. s= strong, m = medium, w = weak, br = broadb. sat. = saturated; conj. = conjugated

The question is based on the concept of Spectroscopy. we have to analyse the spectra provided and…

C-H bend 1470-1430 and 1375-1365 Alkenes =C-H stretch 3100-3010 C=C stretch 1680-1640 (sat.), 1630-1590 (conj. 995-685 C-H bend Alkynes =C-H stretch 3300-3200 C=C stretch 2250-2100 Aromatic C-H stretch 3080-3020 C=C stretch 1650-1580 C-H bend 900-680 Alcohols O-H stretch 3650-3550 3550-3300 1260-1000 C-O stretch Amines N-H stretch 3500-3100 3000 2000 IS00 1000 S00 Nitriles HAVENUMBERI CEN stretch 2280-2200 Aldehydes C-H stretch C-O stretch 2900-2820 and 2775–2700 1740-1720 (sat.), 1705-1680 (conj. Ketones C-O stretch 1725-1705 (sat.), 1685–1665 (conj.I `H Esters C-O stretch C-O stretch 1750-1735 (sat.), 1730–1715 (conj. H,C OCH,CH, 1250-1160 H,C Acids O-H stretch C=O stretch 3500-2500 Ethyl acetate 1725-1700 (sat.), 1715–1680 (conj.l p-Anisaldehyde Amides N-H stretch C-O sretch 3500-3150 1680-1630 Anhydrides C-O stretch C-O stretch 1850-1800 and 1790-1740 1050-900 `CH, Acid chlorides C=O stretch C 1820-1770 Nitro 1660-1490 and 1390-1260 NO, stretch Benzoic acid e a.s strong, m = medium, w = weak, br = broad b. sat. - saturated; conj, - conjugated

C-H bend 1470-1430 and 1375-1365 Alkenes =C-H stretch 3100-3010 C=C stretch 1680-1640 (sat.), 1630-1590 (conj. 995-685 C-H bend Alkynes =C-H stretch 3300-3200 C=C stretch 2250-2100 Aromatic C-H stretch 3080-3020 C=C stretch 1650-1580 C-H bend 900-680 Alcohols O-H stretch 3650-3550 3550-3300 1260-1000 C-O stretch Amines N-H stretch 3500-3100 3000 2000 IS00 1000 S00 Nitriles HAVENUMBERI CEN stretch 2280-2200 Aldehydes C-H stretch C-O stretch 2900-2820 and 2775–2700 1740-1720 (sat.), 1705-1680 (conj. Ketones C-O stretch 1725-1705 (sat.), 1685–1665 (conj.I `H Esters C-O stretch C-O stretch 1750-1735 (sat.), 1730–1715 (conj. H,C OCH,CH, 1250-1160 H,C Acids O-H stretch C=O stretch 3500-2500 Ethyl acetate 1725-1700 (sat.), 1715–1680 (conj.l p-Anisaldehyde Amides N-H stretch C-O sretch 3500-3150 1680-1630 Anhydrides C-O stretch C-O stretch 1850-1800 and 1790-1740 1050-900 `CH, Acid chlorides C=O stretch C 1820-1770 Nitro 1660-1490 and 1390-1260 NO, stretch Benzoic acid e a.s strong, m = medium, w = weak, br = broad b. sat. - saturated; conj, - conjugated

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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