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(c) Consider the steroid androstane provided below: 3 10 CH3 11 11 H 13 7 H CH3 (i) Draw out the full structure of androstane-3ẞ,11ẞ-diol (ii) Provide a synthetic strategy (including reagents) to access 11ẞ-acetoxyandrostan- 3ẞ-ol from androstane-3ẞ,11ẞ-diol. (iii) Predict which alcohol group of androstane-3ẞ,11ẞ-diol would oxidise faster to provide the corresponding ketone and explain why.

(c) Consider the steroid androstane provided below: 3 10 CH3 11 11 H 13 7 H CH3 (i) Draw out the full structure of androstane-3ẞ,11ẞ-diol (ii) Provide a synthetic strategy (including reagents) to access 11ẞ-acetoxyandrostan- 3ẞ-ol from androstane-3ẞ,11ẞ-diol. (iii) Predict which alcohol group of androstane-3ẞ,11ẞ-diol would oxidise faster to provide the corresponding ketone and explain why.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(c) Consider the steroid androstane provided below: 3 10 CH3 11 11 H 13 7 H CH3 (i) Draw out the full structure of androstane-3ẞ,11ẞ-diol (ii) Provide a synthetic strategy (including reagents) to access 11ẞ-acetoxyandrostan- 3ẞ-ol from androstane-3ẞ,11ẞ-diol. (iii) Predict which alcohol group of androstane-3ẞ,11ẞ-diol would oxidise faster to provide the corresponding ketone and explain why.
Transcribed Image Text:(c) Consider the steroid androstane provided below: 3 10 CH3 11 11 H 13 7 H CH3 (i) Draw out the full structure of androstane-3ẞ,11ẞ-diol (ii) Provide a synthetic strategy (including reagents) to access 11ẞ-acetoxyandrostan- 3ẞ-ol from androstane-3ẞ,11ẞ-diol. (iii) Predict which alcohol group of androstane-3ẞ,11ẞ-diol would oxidise faster to provide the corresponding ketone and explain why.
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