By considering these half-reactions and their standard reduction potentials, Pr2+ + 2 e -→ Pt E° = 1.2 V NO, + 4 H30 + 3 e¯ → NO + 6 H;O E° = 0.96 V PtCl + 2 e –→ Pt + 4 CI" E° = 0.73 V account for the fact that platinum will dissolve in a mix- ture of hydrochloric acid and nitric acid (aqua regia) but will not dissolve in either acid alone.

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By considering these half-reactions and their standard
reduction potentials,
Pr2+ + 2 e -→ Pt
E° = 1.2 V
NO, + 4 H30 + 3 e¯ → NO + 6 H;O
E° = 0.96 V
PtCl + 2 e –→ Pt + 4 CI"
E° = 0.73 V
account for the fact that platinum will dissolve in a mix-
ture of hydrochloric acid and nitric acid (aqua regia) but
will not dissolve in either acid alone.
Transcribed Image Text:By considering these half-reactions and their standard reduction potentials, Pr2+ + 2 e -→ Pt E° = 1.2 V NO, + 4 H30 + 3 e¯ → NO + 6 H;O E° = 0.96 V PtCl + 2 e –→ Pt + 4 CI" E° = 0.73 V account for the fact that platinum will dissolve in a mix- ture of hydrochloric acid and nitric acid (aqua regia) but will not dissolve in either acid alone.
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