Br Br „Me Me Br Me Br Me Br Me Ме A В D F Me Br Me Ме Br Br Br Br -Br Me Me G J 1. Which 2 isomers would react fastest in an SN2 reaction? 2. Which 4 isomers could participate in both SN1 and E2? 3. Which 4 isomers could create terminal alkenes in bimolecular elimination? 4. Which 2 isomers would not work in E1/E2 but could react in SN1/SN2? 5. Which 4 isomers would not participate in substitution or elimination? 6. Which isomer could participate in SN1 but not SN2? 7. Which 3 isomers contain secondary leaving groups? 8. Which 3 isomers could create resonance stabilized carbocations? 1

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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7.+ 8.

**Title: Understanding Reactivity of C₄H₇Br Constitutional Isomers**

**Introduction**

In this lesson, we explore twelve constitutional isomers with the molecular formula C₄H₇Br. Your task is to determine how these isomers react in substitution and elimination reactions. Assume no rearrangements occur during these reactions.

**Isomer Structures**

The isomers are labeled from A to L. The structural formula of each isomer, featuring a different arrangement of carbon, hydrogen, and bromine, is provided.

**Questions**

1. **Which 2 isomers would react fastest in an Sn2 reaction?**

2. **Which 4 isomers could participate in both Sn1 and E2 reactions?**

3. **Which 4 isomers could create terminal alkenes in bimolecular elimination?**

4. **Which 2 isomers would not work in E1/E2 but could react in Sn1/Sn2?**

5. **Which 4 isomers would not participate in substitution or elimination?**

6. **Which isomer could participate in Sn1 but not Sn2?**

7. **Which 3 isomers contain secondary leaving groups?**

8. **Which 3 isomers could create resonance stabilized carbocations?**

**Conclusion**

By examining these isomers, students can better understand the reactivity patterns of different molecular structures in chemical reactions such as substitution and elimination. This knowledge is crucial for predicting reaction outcomes and designing synthetic pathways in organic chemistry.
Transcribed Image Text:**Title: Understanding Reactivity of C₄H₇Br Constitutional Isomers** **Introduction** In this lesson, we explore twelve constitutional isomers with the molecular formula C₄H₇Br. Your task is to determine how these isomers react in substitution and elimination reactions. Assume no rearrangements occur during these reactions. **Isomer Structures** The isomers are labeled from A to L. The structural formula of each isomer, featuring a different arrangement of carbon, hydrogen, and bromine, is provided. **Questions** 1. **Which 2 isomers would react fastest in an Sn2 reaction?** 2. **Which 4 isomers could participate in both Sn1 and E2 reactions?** 3. **Which 4 isomers could create terminal alkenes in bimolecular elimination?** 4. **Which 2 isomers would not work in E1/E2 but could react in Sn1/Sn2?** 5. **Which 4 isomers would not participate in substitution or elimination?** 6. **Which isomer could participate in Sn1 but not Sn2?** 7. **Which 3 isomers contain secondary leaving groups?** 8. **Which 3 isomers could create resonance stabilized carbocations?** **Conclusion** By examining these isomers, students can better understand the reactivity patterns of different molecular structures in chemical reactions such as substitution and elimination. This knowledge is crucial for predicting reaction outcomes and designing synthetic pathways in organic chemistry.
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