Both OH groups of the B,B-diol react with excess ethyl chloroformate, but only one OH group of the B,a-diol reacts under the same conditions. Explain the difference in reactivity. сн, сн, оtа НО" "ОН CH3CH2OČCI CH3CH,OCO "OÇOCH2CH3 Н 5a-cholestane-3B,7B-diol Н CH3CH2OČCI НО HO CH3CH2OCO Н 5a-cholestane-3ß,7a-diol Н

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Both OH groups of the B,B-diol react with excess ethyl chloroformate, but only one OH group of the B,a-diol reacts under the same conditions.
Explain the difference in reactivity.
сн, сн, оtа
НО"
"ОН
CH3CH2OČCI
CH3CH,OCO
"OÇOCH2CH3
Н
5a-cholestane-3B,7B-diol
Н
CH3CH2OČCI
НО
HO
CH3CH2OCO
Н
5a-cholestane-3ß,7a-diol
Н
Transcribed Image Text:Both OH groups of the B,B-diol react with excess ethyl chloroformate, but only one OH group of the B,a-diol reacts under the same conditions. Explain the difference in reactivity. сн, сн, оtа НО" "ОН CH3CH2OČCI CH3CH,OCO "OÇOCH2CH3 Н 5a-cholestane-3B,7B-diol Н CH3CH2OČCI НО HO CH3CH2OCO Н 5a-cholestane-3ß,7a-diol Н
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