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Binary system 1-Chlorobutane (1) and Chlorobenzene (2) conform closely to Raoult's Law. The vapor pressure for the pure species are given by Antoine equation: By In Pat (kPa) = A, T('C)+C, Antoine coefficients for 1-Chlorobutane (1) and Chlorobenzene (2) are given in Table Q2. Table Q2: Antoine Coefficients Ai Bi Ci Component 13.7965 2723.73 218.265 1-Chlorobutane (1) 13.8635 3174.78 211.700 Chlorobenzene (2) (i) Prepare a graph showing P vs x1 and P vs y1, for a temperature of T(°C). (ii) Calculate the Bubble-P and Dew-P for the solution of overall composition z1 at T (°C) (iii) Prepare a graph showing T vs x, and T vs y1, for a pressure of 80 kPa. (iv) Calculate the Bubble-T and Dew-T for the solution of overall composition z1 at P = 80 kPa. (v) Discuss the observations made in the parts (i) to (iv).

Binary system 1-Chlorobutane (1) and Chlorobenzene (2) conform closely to Raoult's Law. The vapor pressure for the pure species are given by Antoine equation: By In Pat (kPa) = A, T('C)+C, Antoine coefficients for 1-Chlorobutane (1) and Chlorobenzene (2) are given in Table Q2. Table Q2: Antoine Coefficients Ai Bi Ci Component 13.7965 2723.73 218.265 1-Chlorobutane (1) 13.8635 3174.78 211.700 Chlorobenzene (2) (i) Prepare a graph showing P vs x1 and P vs y1, for a temperature of T(°C). (ii) Calculate the Bubble-P and Dew-P for the solution of overall composition z1 at T (°C) (iii) Prepare a graph showing T vs x, and T vs y1, for a pressure of 80 kPa. (iv) Calculate the Bubble-T and Dew-T for the solution of overall composition z1 at P = 80 kPa. (v) Discuss the observations made in the parts (i) to (iv).

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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NOTE: Z1=0.68 , T=92 (C)

 

Binary system 1-Chlorobutane (1) and Chlorobenzene (2) conform closely to Raoult's Law. The vapor pressure for the pure species are given by Antoine equation: B, In P,oat (kPa) = A, - T('C)+C, Antoine coefficients for 1-Chlorobutane (1) and Chlorobenzene (2) are given in Table Q2. Table Q2: Antoine Coefficients Component Ai Bi Ci 1-Chlorobutane (1) 13.7965 2723.73 218.265 Chlorobenzene (2) 13.8635 3174.78 211.700 (i) Prepare a graph showing P vs x, and P vs y1, for a temperature of T(°C). (ii) Calculate the Bubble-P and Dew-P for the solution of overall composition zi at T (°C) (iii) Prepare a graph showing T vs x, and T vs y,, for a pressure of 80 kPa. (iv) Calculate the Bubble-T and Dew-T for the solution of overall composition z1 at P = 80 kPa. (v) Discuss the observations made in the parts (i) to (iv).
Transcribed Image Text:Binary system 1-Chlorobutane (1) and Chlorobenzene (2) conform closely to Raoult's Law. The vapor pressure for the pure species are given by Antoine equation: B, In P,oat (kPa) = A, - T('C)+C, Antoine coefficients for 1-Chlorobutane (1) and Chlorobenzene (2) are given in Table Q2. Table Q2: Antoine Coefficients Component Ai Bi Ci 1-Chlorobutane (1) 13.7965 2723.73 218.265 Chlorobenzene (2) 13.8635 3174.78 211.700 (i) Prepare a graph showing P vs x, and P vs y1, for a temperature of T(°C). (ii) Calculate the Bubble-P and Dew-P for the solution of overall composition zi at T (°C) (iii) Prepare a graph showing T vs x, and T vs y,, for a pressure of 80 kPa. (iv) Calculate the Bubble-T and Dew-T for the solution of overall composition z1 at P = 80 kPa. (v) Discuss the observations made in the parts (i) to (iv).
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