Below is a proposed mechanism for the chlorination of methane: step1 CH4(g)+Cl2(g)⇀↽CH3(g)+HCl(g)+Cl∙ slow step2 CH3(g)+Cl2(g)⇀↽CH3Cl(g)+Cl∙ fast a. Write the overall chemical reaction and write an overall rate expression for the appearance of CH3Cl (g). Note that this rate expression can include the concentration of intermediates. b. Using your answer to part b, write the rate expression for the change in concentration of CH3 (g). c. Using the steady state approximation, give an expression for the appearance of CH3Cl (g) that does not depend on the concentration of CH3 (g). Note that the first reaction is reversible and the second is not.
Below is a proposed mechanism for the chlorination of methane: step1 CH4(g)+Cl2(g)⇀↽CH3(g)+HCl(g)+Cl∙ slow step2 CH3(g)+Cl2(g)⇀↽CH3Cl(g)+Cl∙ fast a. Write the overall chemical reaction and write an overall rate expression for the appearance of CH3Cl (g). Note that this rate expression can include the concentration of intermediates. b. Using your answer to part b, write the rate expression for the change in concentration of CH3 (g). c. Using the steady state approximation, give an expression for the appearance of CH3Cl (g) that does not depend on the concentration of CH3 (g). Note that the first reaction is reversible and the second is not.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
Below is a proposed mechanism for the chlorination of methane:
step1 CH4(g)+Cl2(g)⇀↽CH3(g)+HCl(g)+Cl∙ slow
step2 CH3(g)+Cl2(g)⇀↽CH3Cl(g)+Cl∙ fast
a. Write the overall
b. Using your answer to part b, write the rate expression for the change in concentration of CH3 (g).
c. Using the steady state approximation, give an expression for the appearance of CH3Cl (g) that does not depend on the concentration of CH3 (g). Note that the first reaction is reversible and the second is not.
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 4 steps
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
![Chemistry: Principles and Reactions](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
![Elementary Principles of Chemical Processes, Bind…](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY