Based on your observations, develop a model to describe how the following changes impact a chemical system at equilibrium Increasing the concentration of a reactant in a system Decreasing the concentration of a reactant in a system Increasing the concentration of a product in a system Decreasing the concentration of a product in a system Adding heat to a system Removing heat from a system Model Format Reactants  Products Change applied Expected direction of shift Explanation Increasing the concentration of a reactant in a system Shift right toward product Because an increase in reactant then the system needs to adjust for equilibrium by shifting to the opposing side Decreasing the concentration of a reactant in a system     Increasing the concentration of a product in a system     Decreasing the concentration of a product in a system

Introductory Chemistry: A Foundation
9th Edition
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Donald J. DeCoste
Chapter17: Equilibrium
Section: Chapter Questions
Problem 11QAP: . What does it mean to say that a state of chemical or physical equilibrium is dynamic?
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Use the table below to complete the following:

Based on your observations, develop a model to describe how the following changes impact a chemical system at equilibrium

Increasing the concentration of a reactant in a system

Decreasing the concentration of a reactant in a system

Increasing the concentration of a product in a system

Decreasing the concentration of a product in a system

Adding heat to a system

Removing heat from a system




Model Format

Reactants  Products

Change applied

Expected direction of shift

Explanation

Increasing the concentration of a reactant in a system

Shift right toward product

Because an increase in reactant then the system needs to adjust for equilibrium by shifting to the opposing side

Decreasing the concentration of a reactant in a system

   

Increasing the concentration of a product in a system

   

Decreasing the concentration of a product in a system

   

Adding heat to a system

Reactants + heat  Products



 

Adding heat to a system

Reactants ⇋   Products + heat

   

Removing heat from a system

Reactants + heat  Products

   

Removing heat from a system

Reactants ⇋   Products + heat

   

 

Part II

Next, you will perform some tests on the iron thiocyanate system described in the equation below and record your observations.  

System

Fe3+(aq)  +  SCN–(aq)    ⇆    FeSCN2+(aq)  +  heat

Yellow       Colorless        Orange-Red

Test Tube

Procedure

Predictions

(what color will

you see)

Observations

1

No tests (control)

 

 

2

Add 0.1M KSCN drop wise until change is observed

*increases concentration of SCN- in the system

Right

Orange redder 

 

3

Add 4.0M NaCl drop wise until change is observed

*decreases concentration of Fe3+ in the system

1.Right 

2. yellow

 

Left and yellow 

4

Add 0.1M Fe(NO3)3 drop wise until change is observed

*increases concentration of Fe3+ in the system

Right 

orange 

 

5

Add 0.05M AgNO3 drop wise until change is observed

*decreases concentration of SCN- in the system

Left 

yellow 

 

6

Place in hot water bath for 1-2 minutes

*adds heat to the reaction system

left 

 

7

Place in ice water bath for 1-2 minutes

*removes heat from the reaction system

 

 

Refined Model - only make additions if the model changed. 

Reactants  Products

Change applied

Expected direction of shift

Explanation

Increasing the concentration of a reactant in a system

   

Decreasing the concentration of a reactant in a system

   

Increasing the concentration of a product in a system

   

Decreasing the concentration of a product in a system

   

Adding heat to a system

Reactants + heat  Products



 

Adding heat to a system

Reactants ⇋   Products + heat

   

Removing heat from a system

Reactants + heat  Products

   

Removing heat from a system

Reactants ⇋   Products + heat

   
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