Based on this figure, answer these questions: a) Starting from a liquid mixture with a composition x1 = 0.4, at which pressure will appear the first vapour? Which will be its composition? b) If such a mixture is put under 430 mmHg of pressure, which will be the compositions of both phases in equilibrium? And their nliq/nvap mol relation? c) Under which pressure will the last drop of liquid disappear? Which will be its composition? Results: a)p ≈ 465 mmHg, y1 ≈ 0.61; b) x1 ≈ 0.32; y1 ≈ 0.52; nliq/nvap ≈ 1.5; c) p ≈ 390 mmHg, x1 ≈ 0.23;

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Based on this figure, answer these questions:

a) Starting from a liquid mixture with a composition x1 = 0.4, at which pressure will appear the first vapour? Which will be its composition?
b) If such a mixture is put under 430 mmHg of pressure, which will be the compositions of both phases in equilibrium? And their nliq/nvap mol relation?
c) Under which pressure will the last drop of liquid disappear? Which will be its composition?
Results: a)p ≈ 465 mmHg, y1 ≈ 0.61; b) x1 ≈ 0.32; y1 ≈ 0.52; nliq/nvap ≈ 1.5; c) p ≈ 390 mmHg, x1 ≈ 0.23;

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a liquid mixture with a composition x1 = 0.4, at which pressure will appear
e Which will be its composition?
kture is put under 430 mmHg of pressure, which will be the compositions of
=quilibrium? And their miq/Mvap mol relation?
pressure will the last drop of liquid disappear? Which will be its composition?
65 mmHg, yı = 0.61; b) x1 × 0.32; yı = 0.52; iq/nvap × 1.5;
Ig, x1 = 0.23;
P (mm Hg)
Transcribed Image Text:800 800 riko ea 700 700 600 600 500 00 400 400 300 300 200 200 0.2 0.4 0.6 0.8 a liquid mixture with a composition x1 = 0.4, at which pressure will appear e Which will be its composition? kture is put under 430 mmHg of pressure, which will be the compositions of =quilibrium? And their miq/Mvap mol relation? pressure will the last drop of liquid disappear? Which will be its composition? 65 mmHg, yı = 0.61; b) x1 × 0.32; yı = 0.52; iq/nvap × 1.5; Ig, x1 = 0.23; P (mm Hg)
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