Based on the thermodynamic properties provided for water, determine the energy change when the temperature of 0.450 kg of water decreased from 103 °C to 42.0 °C. NOTE: MOLAR specfic heat capacities (Cp.n) are given here! Property Value Units Melting point °C Boiling point 100.0 °C AHfus 6.01 kJ/mol ΔΗap 40.67 kJ/mol Gp (s) 37.1 J/mol · °C 75.3 J/mol · °C Go (8) 33.6 J/mol · °C kJ

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter12: Thermodynamic Processes And Thermochemistry
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Based on the thermodynamic properties provided for water, determine the energy change when the temperature of 0.450 kg of water decreased from 103 °C to 42.0 °C. **NOTE: MOLAR specific heat capacities (\(c_{p,n}\)) are given here!**

| Property         | Value  | Units        |
|------------------|--------|--------------|
| Melting point    | 0      | °C           |
| Boiling point    | 100.0  | °C           |
| \(\Delta H_{fus}\) | 6.01   | kJ/mol       |
| \(\Delta H_{vap}\) | 40.67  | kJ/mol       |
| \(c_p (\text{s})\)   | 37.1   | J/mol·°C    |
| \(c_p (\text{l})\)   | 75.3   | J/mol·°C    |
| \(c_p (\text{g})\)   | 33.6   | J/mol·°C    |

[                                         ] kJ

The table outlines the phase transition points and molar specific heat capacities for solid, liquid, and gaseous water. The enthalpy changes for fusion and vaporization are also provided, which are crucial for calculating energy changes during phase transitions. Use these values to compute the energy change for the given conditions.
Transcribed Image Text:Based on the thermodynamic properties provided for water, determine the energy change when the temperature of 0.450 kg of water decreased from 103 °C to 42.0 °C. **NOTE: MOLAR specific heat capacities (\(c_{p,n}\)) are given here!** | Property | Value | Units | |------------------|--------|--------------| | Melting point | 0 | °C | | Boiling point | 100.0 | °C | | \(\Delta H_{fus}\) | 6.01 | kJ/mol | | \(\Delta H_{vap}\) | 40.67 | kJ/mol | | \(c_p (\text{s})\) | 37.1 | J/mol·°C | | \(c_p (\text{l})\) | 75.3 | J/mol·°C | | \(c_p (\text{g})\) | 33.6 | J/mol·°C | [                                         ] kJ The table outlines the phase transition points and molar specific heat capacities for solid, liquid, and gaseous water. The enthalpy changes for fusion and vaporization are also provided, which are crucial for calculating energy changes during phase transitions. Use these values to compute the energy change for the given conditions.
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