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(b). (i). The electronic absorption spectrum of aqueous [Ti(OH2)6]?* (stable under acidic conditions) exhibits two well-separated bands at 430 and 650 nm. These two bands indicate the appearance of 'd-d' transitions, whereas the aqueous [Ti(OH2)6]3+ exhibits one absorption band at 490 nm with a shoulder at 580 nm. By drawing the splitting orbital diagram, explain clearly the difference between these absorption bands of [Ti(OH2)6]?+ and [Ti(OH2)s]3+.

(b). (i). The electronic absorption spectrum of aqueous [Ti(OH2)6]?* (stable under acidic conditions) exhibits two well-separated bands at 430 and 650 nm. These two bands indicate the appearance of 'd-d' transitions, whereas the aqueous [Ti(OH2)6]3+ exhibits one absorption band at 490 nm with a shoulder at 580 nm. By drawing the splitting orbital diagram, explain clearly the difference between these absorption bands of [Ti(OH2)6]?+ and [Ti(OH2)s]3+.

Chemistry
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Kindly answer this question i & ii

(b). (i). The electronic absorption spectrum of aqueous [Ti(OH2)6]?+ (stable under acidic conditions) exhibits two well-separated bands at 430 and 650 nm. These two bands indicate the appearance of 'd-d' transitions, whereas the aqueous [Ti(OH2)6]3+ exhibits one absorption band at 490 nm with a shoulder at 580 nm. By drawing the splitting orbital diagram, explain clearly the difference between these absorption bands of [Ti(OH2)6]?* and [Ti(OH2)6]*. (ii). Determine whether these octahedral complexes, [CrF6]“, [Fe(CN)6]4 and [Fe(CN)6]³ will be affected by the Jahn-Teller distortion.
Transcribed Image Text:(b). (i). The electronic absorption spectrum of aqueous [Ti(OH2)6]?+ (stable under acidic conditions) exhibits two well-separated bands at 430 and 650 nm. These two bands indicate the appearance of 'd-d' transitions, whereas the aqueous [Ti(OH2)6]3+ exhibits one absorption band at 490 nm with a shoulder at 580 nm. By drawing the splitting orbital diagram, explain clearly the difference between these absorption bands of [Ti(OH2)6]?* and [Ti(OH2)6]*. (ii). Determine whether these octahedral complexes, [CrF6]“, [Fe(CN)6]4 and [Fe(CN)6]³ will be affected by the Jahn-Teller distortion.
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