B. Calculation of the rate of reaction at selected times. Calculate the rate of the reaction at each time indicated in the table. Express the rate in units of M/sec. Show the calculation of the 1000 second values. chemicai leaction TIME (IN SECONDS) [t-BuCl], RATE, t-Qucl + H20 1000 thuoH + HCI 2000 3000 K = 3.1 10 sec! -5 1-

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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Solvent: 50:50 water:isopropyl alcohol (v/v)
Temperature:
Volume of pure t-BuCl sample: \, 06 ML
(3 sig figs.)
Initial volume, V, of t-BuCl solution: |0l m
(3 sig figs.)
Calculated initial concentration of t-BuCl, [t-BuCl],: ¶. SI mol (3 sig figs.)
Molarity of NaOH: . I50 m
(3 sig figs.)
TIME
BURET
READING
TOTAL VOLUME
OF NAOH ADDED
V, NAOH (mL)
EXPIRED
CALCULATED
TIME OF DAY
In[t-BuCl],
(SECONDS)
[t-BuCl],
t
9.81 M 22ss M
16.1mL
420 sec 18.2ml
19.3 mL
0.0 mL
6:43
O sec
21 me 9.61
3.2
5.3
6.6
65
76
2.26
2.25
2.33
222
221
220
2.20
219
218
6:50
6:56
7:02
9.50
9.31
140
21.9 mL
22.6 mL
B.1
24.2
25.1mL
7:07
1440
1740
2040
2340
9946
9946
26.5
9.20
911
906
4.97
7:12
7:17
mL
7:22
7:77
7:32
mL
9.0
10.2
4
26.3
26.5 m
6.59
8.876 218
mL
2
7:37
10.4 v
1
3246
Experimental Data
Transcribed Image Text:Solvent: 50:50 water:isopropyl alcohol (v/v) Temperature: Volume of pure t-BuCl sample: \, 06 ML (3 sig figs.) Initial volume, V, of t-BuCl solution: |0l m (3 sig figs.) Calculated initial concentration of t-BuCl, [t-BuCl],: ¶. SI mol (3 sig figs.) Molarity of NaOH: . I50 m (3 sig figs.) TIME BURET READING TOTAL VOLUME OF NAOH ADDED V, NAOH (mL) EXPIRED CALCULATED TIME OF DAY In[t-BuCl], (SECONDS) [t-BuCl], t 9.81 M 22ss M 16.1mL 420 sec 18.2ml 19.3 mL 0.0 mL 6:43 O sec 21 me 9.61 3.2 5.3 6.6 65 76 2.26 2.25 2.33 222 221 220 2.20 219 218 6:50 6:56 7:02 9.50 9.31 140 21.9 mL 22.6 mL B.1 24.2 25.1mL 7:07 1440 1740 2040 2340 9946 9946 26.5 9.20 911 906 4.97 7:12 7:17 mL 7:22 7:77 7:32 mL 9.0 10.2 4 26.3 26.5 m 6.59 8.876 218 mL 2 7:37 10.4 v 1 3246 Experimental Data
B. Calculation of the rate of reaction at selected times.
Calculate the rate of the reaction at each time indicated in the table. Express the rate
in units of M/sec. Show the calculation of the 1000 second values.
chemicai ledctian
TIME (IN SECONDS)
[t-BuC],
RATE,
t-Qucl+
H20
1000
thuoH + HCI
2000
3000
K= 3.1 10 sec-!
Transcribed Image Text:B. Calculation of the rate of reaction at selected times. Calculate the rate of the reaction at each time indicated in the table. Express the rate in units of M/sec. Show the calculation of the 1000 second values. chemicai ledctian TIME (IN SECONDS) [t-BuC], RATE, t-Qucl+ H20 1000 thuoH + HCI 2000 3000 K= 3.1 10 sec-!
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