b) The diagram below shows the reaction scheme for benzene and its derivatives: соон CH,CI, AICI, Br2, uv Y i) Draw compound X. ii) What reagents are required to carry out the conversion I and II ? iii) Name compound Y
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![b) The diagram below shows the reaction scheme for benzene and its derivatives:
СООН
CH,CI, AICI,
Br2, uv
.CI
Y
i) Draw compound X.
ii) What reagents are required to carry out the conversion I and II ?
iii) Name compound Y](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb1615753-f00a-45ac-81bc-72af0a089b6d%2F4c78e7e4-cf1c-428c-8258-9608c24c9cdd%2Fcsgz47_processed.jpeg&w=3840&q=75)
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- a) Give the molecular formula and draw the skeletal structure for 3-bromo-3- methylhexane. b) Name (including E/Z stereochemistry) the FIVE alkenes that can produce 3-bromo-3- methylhexane on reaction with HBr. Draw the skeletal structure of each molecule.??? c) Define the type of stereoisomerism present in 3-bromo-3-methylhexane. Name and draw the tetrahedral representation of the two stereoisomers?. d) For the base-catalysed hydrolysis of 3-bromo-3-methylhexane (i.e. reaction with the nucleophile OH-): i) ii) iii) iv) State whether the reaction is likely to proceed by an SN1 or SN2 mechanism, and explain your choice Give the likely rate law for the reaction. Explain your choice. For the reaction intermediate, draw its structure and give the VSEPR description of the geometry at the reaction centre Give the names and draw the structures of the two reaction products. Explain your conclusions1. Draw structural formulas for 1-bromobutane, 2-bromobutane, 2-bromo-2- methylpropane, 1-bromo-2-methylpropane, and 1-bromo-2,2-dimethylpropane. Classify each compound as a primary halide, secondary halide, or tertiary halide. 2. Draw structural formulas for acetone and ethanol. Which solvent is more polar? Explain. 3. A student wishes to determine the rate law for the reaction A +B → C. The student doubles the concentration of A while holding the concentration of B constant and finds that the rate of the reaction doubles. The student then doubles the concentration of B while holding the concentration of A constant and finds that the rate is unchanged. Write the rate law for this reaction. (Refer to a general chemistry text, if necessary.) Experimental Procedure S aOrganic chemistry - Alcohols
- A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis gave CH3(CH2), CO₂H and HO₂CCH2CH2CH2CH2CO₂H as the only products. Draw a reasonable structure for this hydrocarbon. Click and drag to start drawing a structure. D:3A) An Alcohol X has the structure of (CH,), C(OH)CH(CH,),. i) State the IUPAC name of alcohol X. i) Outline the mechanism for the reaction occurring when alcohol X is converted into 2,3-dimethylbut-2-ene in the presence of a strong acid. i) Name the reaction in part ii). iv) Draw the structure and state the IUPAC name of an isomer of 2,3-dimethyl-2- butene which is also formed in the reaction. v) Explain why two products are obtained. vi) Write an equation for the reaction between alcohol X and ethanoyl chloride. vii) Outline a mechanism for this reaction, using ROH to represent the alcohol in the mechanism.
- 2. The molecules shown below are four terpineol isomers. They are isolated from plants and have distinct aromas. For example, a -terpineol is a common perfume ingredient and smells similar to lilacs. Hol H-O- a-terpineol B-terpineol Y-terpineol 4-terpineol A) Draw a structural isomer of terpineol that meet the following criteria. You should draw one unique structure for each set. You must draw each molecule twice, once as a skeletal structure and once as a complete Lewis structure showing all atoms, bonds, and lone pairs of electrons. i. Does not have a ring. ii. Has an E alkene. iii. Has a secondary alcohol. iv. Does not contain an alcohol. B) Draw a complete Lewis structure of a-terpineol showing all bonds, atoms and lone pairs of electrons.The ACS exam at the end of this semester covers a limited amount of IUPAC nomenclature mostly from Organic I. An example is given below, what is the IUPAC name of of the compound whose structure is shown in the box? A) E-1- butylidene-1-iodo-propane B) E-5-iodo-4-heptene C) E-1-(1-iodopropylidene)-butane D) E-3-iodo-3-heptene A В2. Draw structures for the following systems. If more than one isomer is possible, draw strcutures for all the possible isomers. Benzene ring with a methyl group and a nitro group (Draw all possible isomers, and name them) Benzene ring connected to a heptane chain (Draw all possible isomers, and name them) 2-benzyl-3- methylbutan-1-ol
- organic chemistry 6) Aniline NH₂ is best prepared by7. Consider the following three step reaction. [4 (a) Add curved arrows in Step [1] to show the movement of electrons. H Lö: HÖ [1] + H-Ci: (b) Use the curved arrows drawn in Step [2] to identify the structure of X. X is converted in Step [3] to phenol and HCI. [2] + H-CI: [3] phenol1. STRUCTURE-DESCRIPTION Draw the structure of a compound that fits the given description. 1. the least water-soluble isomer of an alcohol with MF C5H₁2O 2. a compound with MF C₂H4O2 that gives a dicarboxylic acid upon reaction with hot KMnO4 3. an disubstituted cyclic ether with MF C4H8O showing a trans geometry. 4. an alkyl halide with MF C4H9Cl that is most reactive via SN1 mechanism
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