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(b) The carbon-carbon bond length of coordinated ethylene in Pt(PPh3)2(1²-C2H4), F, is 1.44 Å, as determined by X-ray crystal structure analysis. The carbon-carbon bond length of free (uncoordinated) ethylene is 1.34 Å. Rationalise this difference in bond length. Sketch relevant molecular orbitals.

(b) The carbon-carbon bond length of coordinated ethylene in Pt(PPh3)2(1²-C2H4), F, is 1.44 Å, as determined by X-ray crystal structure analysis. The carbon-carbon bond length of free (uncoordinated) ethylene is 1.34 Å. Rationalise this difference in bond length. Sketch relevant molecular orbitals.

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Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(b) The carbon-carbon bond length of coordinated ethylene in Pt(PPh3)2(1²-C2H4), F, is 1.44 Å, as determined by X-ray crystal structure analysis. The carbon-carbon bond length of free (uncoordinated) ethylene is 1.34 Å. Rationalise this difference in bond length. Sketch relevant molecular orbitals.
Transcribed Image Text:(b) The carbon-carbon bond length of coordinated ethylene in Pt(PPh3)2(1²-C2H4), F, is 1.44 Å, as determined by X-ray crystal structure analysis. The carbon-carbon bond length of free (uncoordinated) ethylene is 1.34 Å. Rationalise this difference in bond length. Sketch relevant molecular orbitals.
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