b) iii versus iv

Chemistry
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Chapter1: Chemical Foundations
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4.
Sl. No.
(i)
(ii)
(iii)
(iv)
(v)
Reaction
[Co(NH3)6]³+ + [Cr(bpy)3]²+
[CO(NH3)5(OH₂)]³+ + [Cr(bpy)]²+
[Ru(phen)3]2+ + [Ru(phen)3]³+
[Ru(OH₂)6]2+ + [Ru(OH₂)6]³+
[Co(OH₂)6]2+ + [Co(OH₂)6]³+
Rate (in M-¹s-¹)
6.9 x 10²
x 104
5
≥ 10²
8.2 x 10²
5.0
With reference to the above-mentioned table, rationalize the trends in the rate of electron transfer
reactions in the following cases:
(a) i versus ii
(b) iii versus iv
(c) iv versus v
Transcribed Image Text:4. Sl. No. (i) (ii) (iii) (iv) (v) Reaction [Co(NH3)6]³+ + [Cr(bpy)3]²+ [CO(NH3)5(OH₂)]³+ + [Cr(bpy)]²+ [Ru(phen)3]2+ + [Ru(phen)3]³+ [Ru(OH₂)6]2+ + [Ru(OH₂)6]³+ [Co(OH₂)6]2+ + [Co(OH₂)6]³+ Rate (in M-¹s-¹) 6.9 x 10² x 104 5 ≥ 10² 8.2 x 10² 5.0 With reference to the above-mentioned table, rationalize the trends in the rate of electron transfer reactions in the following cases: (a) i versus ii (b) iii versus iv (c) iv versus v
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