At the end of the experiment, it was discovered that the thermometer had not been calibrated. When it was calibrated, it was found that the thermometer read 0.50 C low. What effect would thus thermometer reading have on the reported change in H neoutzn calculated above?
At the end of the experiment, it was discovered that the thermometer had not been calibrated. When it was calibrated, it was found that the thermometer read 0.50 C low. What effect would thus thermometer reading have on the reported change in H neoutzn calculated above?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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At the end of the experiment, it was discovered that the thermometer had not been calibrated. When it was calibrated, it was found that the thermometer read 0.50 C low. What effect would thus thermometer reading have on the reported change in H neoutzn calculated above?

Transcribed Image Text:**Text from the Image:**
© 1988 Cengage Learning
2. When a neutralization reaction was carried out using 100.0 mL of 0.7980 M NH₃ water and 100.0 mL of 0.7940 M acetic acid, ΔT was found to be 4.76°C. The specific heat of the reaction mixture was 4.104 J/g·K, and its density was 1.03 g/mL. The calorimeter constant was 3.36 J/°C.
(1) Calculate ΔH_neutzn for the reaction of NH₃ and acetic acid.
- heat absorbed by reaction = (volume)(density)(ΔT)(specific heat)
= (200 mL)(1.03 g/mL)(4.76)(4.104 J/g·K)
= 400.424 J
- heat absorbed by calorimeter = calorimeter constant(ΔT)
= 3.36 J/°C(4.76 °C)
= 15.99 J
- total heat = 400.424 J + 15.99 J
= 416.423 J
- moles of NH₃ = (0.100 L)(0.7980 M) = 0.0798 mol
- moles of CH₃COOH = (0.100 L)(0.7940 M) = 0.0794 mol
limiting reagent → ignore
ΔH_neutrn = total heat / moles
ΔH_neutrn = 416.423 J / 0.0794 mol
= Fill kJ/mol
(2) At the end of the experiment, it was discovered that the thermometer had not been calibrated. When it was calibrated, it was found that the thermometer read 0.5°C low. What effect would this thermometer reading have on the reported ΔH_neutzn calculated in (2) above?
---
Note: The calculation for ΔH_neutrn is not completed in the image and is marked as "Fill kJ/mol."
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