At the end of the experiment, it was discovered that the thermometer had not been calibrated. When it was calibrated, it was found that the thermometer read 0.50 C low. What effect would thus thermometer reading have on the reported change in H neoutzn calculated above?

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At the end of the experiment, it was discovered that the thermometer had not been calibrated. When it was calibrated, it was found that the thermometer read 0.50 C low. What effect would thus thermometer reading have on the reported change in H neoutzn calculated above?
**Text from the Image:**

© 1988 Cengage Learning

2. When a neutralization reaction was carried out using 100.0 mL of 0.7980 M NH₃ water and 100.0 mL of 0.7940 M acetic acid, ΔT was found to be 4.76°C. The specific heat of the reaction mixture was 4.104 J/g·K, and its density was 1.03 g/mL. The calorimeter constant was 3.36 J/°C.

(1) Calculate ΔH_neutzn for the reaction of NH₃ and acetic acid. 

- heat absorbed by reaction = (volume)(density)(ΔT)(specific heat)
  = (200 mL)(1.03 g/mL)(4.76)(4.104 J/g·K)
  = 400.424 J

- heat absorbed by calorimeter = calorimeter constant(ΔT)
  = 3.36 J/°C(4.76 °C)
  = 15.99 J

- total heat = 400.424 J + 15.99 J
  = 416.423 J

- moles of NH₃ = (0.100 L)(0.7980 M) = 0.0798 mol
- moles of CH₃COOH = (0.100 L)(0.7940 M) = 0.0794 mol

limiting reagent → ignore 

ΔH_neutrn = total heat / moles
ΔH_neutrn = 416.423 J / 0.0794 mol 
= Fill kJ/mol

(2) At the end of the experiment, it was discovered that the thermometer had not been calibrated. When it was calibrated, it was found that the thermometer read 0.5°C low. What effect would this thermometer reading have on the reported ΔH_neutzn calculated in (2) above?

---

Note: The calculation for ΔH_neutrn is not completed in the image and is marked as "Fill kJ/mol."
Transcribed Image Text:**Text from the Image:** © 1988 Cengage Learning 2. When a neutralization reaction was carried out using 100.0 mL of 0.7980 M NH₃ water and 100.0 mL of 0.7940 M acetic acid, ΔT was found to be 4.76°C. The specific heat of the reaction mixture was 4.104 J/g·K, and its density was 1.03 g/mL. The calorimeter constant was 3.36 J/°C. (1) Calculate ΔH_neutzn for the reaction of NH₃ and acetic acid. - heat absorbed by reaction = (volume)(density)(ΔT)(specific heat) = (200 mL)(1.03 g/mL)(4.76)(4.104 J/g·K) = 400.424 J - heat absorbed by calorimeter = calorimeter constant(ΔT) = 3.36 J/°C(4.76 °C) = 15.99 J - total heat = 400.424 J + 15.99 J = 416.423 J - moles of NH₃ = (0.100 L)(0.7980 M) = 0.0798 mol - moles of CH₃COOH = (0.100 L)(0.7940 M) = 0.0794 mol limiting reagent → ignore ΔH_neutrn = total heat / moles ΔH_neutrn = 416.423 J / 0.0794 mol = Fill kJ/mol (2) At the end of the experiment, it was discovered that the thermometer had not been calibrated. When it was calibrated, it was found that the thermometer read 0.5°C low. What effect would this thermometer reading have on the reported ΔH_neutzn calculated in (2) above? --- Note: The calculation for ΔH_neutrn is not completed in the image and is marked as "Fill kJ/mol."
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