At room temperature and pressure RbI crystallizes with theNaCl-type structure. (a) Use ionic radii to predict the length ofthe cubic unit cell edge. (b) Use this value to estimate the density.(c) At high pressure the structure transforms to one witha CsCl-type structure. (c) Use ionic radii to predict the lengthof the cubic unit cell edge for the high-pressure form of RbI.(d) Use this value to estimate the density. How does this densitycompare with the density you calculated in part (b)?

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter21: The Solid State: Crystals
Section: Chapter Questions
Problem 21.47E
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At room temperature and pressure RbI crystallizes with the
NaCl-type structure. (a) Use ionic radii to predict the length of
the cubic unit cell edge. (b) Use this value to estimate the density.
(c) At high pressure the structure transforms to one with
a CsCl-type structure. (c) Use ionic radii to predict the lengthof the cubic unit cell edge for the high-pressure form of RbI.
(d) Use this value to estimate the density. How does this density
compare with the density you calculated in part (b)?

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