At elevated temperatures, methyllsonitrile (CH3NC) isomerizes to acetonitrile (CH3CN): CH3NC (g) CH3CN (g) The reaction is first order in methylisonitrile. The attached graph shows data for the reaction obtained at 198.9 °C and the equation of the line is y= -5.1 x 10-5 sx + 5.05. 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 0. 10,000 20,000 30,000 Time (s) The rate law for the reaction is Select one: O A. rate = -5.1 x 10-5 s [CH3NC]? O B. rate 5.1 x 10-5 s-1 [CH3NC] O C. rate 5.1 x 10-5 s-1 [CH3NC]2 OD. rate -5.1 x 10-5 s-1 [CH,NC] O E. rate 5.05 s [CH3NC]2 In pressure, CH,NC

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### Isomerization of Methyisonitrile (CH3NC) to Acetonitrile (CH3CN) at Elevated Temperatures

#### Chemical Reaction:
At elevated temperatures, methyisonitrile (CH3NC) isomerizes to acetonitrile (CH3CN) as represented by the following chemical equation:

\[ \text{CH}_3\text{NC (g)} \rightarrow \text{CH}_3\text{CN (g)} \]

#### Kinetic Analysis:

The reaction is first-order in methyisonitrile. The following graph provides data obtained for the reaction at a temperature of 198.9°C.

#### Graph Description:

The graph is a plot of the pressure of CH3NC (in arbitrary units) against time (in seconds). The data points form a near-straight line, indicating first-order kinetics. The equation of the line derived from this plot is:

\[ y = -5.1 \times 10^{-5} \text{s}^{-1} \cdot x + 5.05 \]

- **Y-axis (vertical)**: Represents the pressure of CH3NC, ranging from 3.4 to 5.2 units.
- **X-axis (horizontal)**: Represents time in seconds (s), ranging from 0 to 30,000 seconds.
  
Points on the graph indicate that as time progresses, the pressure of CH3NC decreases, suggesting a decrease in its concentration due to the isomerization process.

#### Rate Law Determination:

Based on the data and the linear equation provided, the rate law for the reaction is to be identified from the following options:

1. \( \text{rate} = -5.1 \times 10^{-5} \text{s}^{-1} [\text{CH}_3\text{NC}]^2 \)
2. \( \text{rate} = 5.1 \times 10^{-5} \text{s}^{-1} [\text{CH}_3\text{NC}] \)
3. \( \text{rate} = 5.1 \times 10^{-5} \text{s}^{-1} [\text{CH}_3\text{NC}]^2 \)
4. \( \text{rate} = -5.1 \times 10^{-5} \text{s}^{-1} [\text{CH
Transcribed Image Text:### Isomerization of Methyisonitrile (CH3NC) to Acetonitrile (CH3CN) at Elevated Temperatures #### Chemical Reaction: At elevated temperatures, methyisonitrile (CH3NC) isomerizes to acetonitrile (CH3CN) as represented by the following chemical equation: \[ \text{CH}_3\text{NC (g)} \rightarrow \text{CH}_3\text{CN (g)} \] #### Kinetic Analysis: The reaction is first-order in methyisonitrile. The following graph provides data obtained for the reaction at a temperature of 198.9°C. #### Graph Description: The graph is a plot of the pressure of CH3NC (in arbitrary units) against time (in seconds). The data points form a near-straight line, indicating first-order kinetics. The equation of the line derived from this plot is: \[ y = -5.1 \times 10^{-5} \text{s}^{-1} \cdot x + 5.05 \] - **Y-axis (vertical)**: Represents the pressure of CH3NC, ranging from 3.4 to 5.2 units. - **X-axis (horizontal)**: Represents time in seconds (s), ranging from 0 to 30,000 seconds. Points on the graph indicate that as time progresses, the pressure of CH3NC decreases, suggesting a decrease in its concentration due to the isomerization process. #### Rate Law Determination: Based on the data and the linear equation provided, the rate law for the reaction is to be identified from the following options: 1. \( \text{rate} = -5.1 \times 10^{-5} \text{s}^{-1} [\text{CH}_3\text{NC}]^2 \) 2. \( \text{rate} = 5.1 \times 10^{-5} \text{s}^{-1} [\text{CH}_3\text{NC}] \) 3. \( \text{rate} = 5.1 \times 10^{-5} \text{s}^{-1} [\text{CH}_3\text{NC}]^2 \) 4. \( \text{rate} = -5.1 \times 10^{-5} \text{s}^{-1} [\text{CH
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