Assume that the reaction: 2 N,0, → 4 NO, + O, proceeds via the following three-step mechanism: N2O5 NO2 + NO3 kp NO, + NO, NO + NO, + O2 k3 2 NO, NO, + NO - where kf and kb represent the forward and backward rate constants for the first step. Derive the differential rate law for [O2] using the steady state approximation, i.e. the assumption that intermediates are consumed at the same rate as they are produced.
Assume that the reaction: 2 N,0, → 4 NO, + O, proceeds via the following three-step mechanism: N2O5 NO2 + NO3 kp NO, + NO, NO + NO, + O2 k3 2 NO, NO, + NO - where kf and kb represent the forward and backward rate constants for the first step. Derive the differential rate law for [O2] using the steady state approximation, i.e. the assumption that intermediates are consumed at the same rate as they are produced.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![6. Assume that the reaction:
2 N,0, → 4 NO, + 0,
→4 NO, + 0,
proceeds via the following three-step mechanism:
kf
N2O5 NO2 + NO3
kb
k2
NO, + NO, NO + NO, + 0,
k3
NO, + NO→2 NO,
where kt and kb represent the forward and backward rate constants for the first
step. Derive the differential rate law for [O2] using the steady state approximation, i.e.
the assumption that intermediates are consumed at the same rate as they are
produced.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc237b1c0-56cb-401b-acfa-bb13ee5c1c79%2Fea14d20d-09b6-4e3f-b207-c6d9372170cf%2Fkdutsp9_processed.jpeg&w=3840&q=75)
Transcribed Image Text:6. Assume that the reaction:
2 N,0, → 4 NO, + 0,
→4 NO, + 0,
proceeds via the following three-step mechanism:
kf
N2O5 NO2 + NO3
kb
k2
NO, + NO, NO + NO, + 0,
k3
NO, + NO→2 NO,
where kt and kb represent the forward and backward rate constants for the first
step. Derive the differential rate law for [O2] using the steady state approximation, i.e.
the assumption that intermediates are consumed at the same rate as they are
produced.
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