Assume as a first approximation that the molar volume of a van der Waals gas and pressure are given by the following equations: RT + (b RT RT V -b V From the previous equations and the fundamental equations of thermodynamics and relations of Maxwell of appropriate Thermodynamics, calculate DH and DS for isothermal compression to 300 K for a given gas, behaving like a van der Waals gas, of 0.1 MPa (MPa = Megapascal) to 10 MPa (MPa = Megapascal). Data: a=0.37P m6 mol² and b=42.90x10-6 m³ mol·' for the considered gas. %3D

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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Assume as a first approximation that the molar volume of a van
der Waals gas and pressure are given by the following equations:
RT
+ (b - RT
RT
a
V -b V²
From the previous equations and the fundamental equations of
thermodynamics and relations of Maxwell of appropriate
Thermodynamics, calculate DH and DS for isothermal
compression to 300 K for a given gas, behaving like a van der
Waals gas, of 0.1 MPa (MPa = Megapascal) to 10 MPa (MPa =
Megapascal). Data: a=0.37Pa m6 mol² and b=42.90x10-6 m³ mol·1
for the considered gas.
Transcribed Image Text:Assume as a first approximation that the molar volume of a van der Waals gas and pressure are given by the following equations: RT + (b - RT RT a V -b V² From the previous equations and the fundamental equations of thermodynamics and relations of Maxwell of appropriate Thermodynamics, calculate DH and DS for isothermal compression to 300 K for a given gas, behaving like a van der Waals gas, of 0.1 MPa (MPa = Megapascal) to 10 MPa (MPa = Megapascal). Data: a=0.37Pa m6 mol² and b=42.90x10-6 m³ mol·1 for the considered gas.
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