As the following data show, removing an electron from N₂ forms an ion with a weaker, longer bond than in the parent molecule, whereas the ion formed from O₂ has a stronger, shorter bond. Explain these facts using the MO diagrams... what else do you need to determine? Be sure to give an explanation below based on Molecular Orbital theory and to show your work using the correct MO diagram on the next page. N₂ N₂+ 0₂ O₂+ Bond energy (kJ/mol) 945 841 Bond length (pm) 110 112 498 121 623 112

As the following data show, removing an electron from N₂ forms an ion with a weaker, longer bond than in the parent molecule, whereas the ion formed from O₂ has a stronger, shorter bond. Explain these facts using the MO diagrams... what else do you need to determine? Be sure to give an explanation below based on Molecular Orbital theory and to show your work using the correct MO diagram on the next page. N₂ N₂+ 0₂ O₂+ Bond energy (kJ/mol) 945 841 Bond length (pm) 110 112 498 121 623 112

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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5. Draw the # and molecular orbitals for the discrete and localized T bonds in the following structures. Indicate any polar- ization these bonds may have in your diagram through the shapes of the discrete bonding and antibonding orbitals. e 6. Show any plausible resonance structures for the molecules given in Exercises 1 and 5. If there are no plausible resonance structures, indicate this (note that the molecule corresponding to letter A is the same in each problem). 7. Discuss the hybridization in the C-C and C-H bonds of cyclopropane, given that the H-C-H bond angle is 118°. withara --- totrachlorida b dingl A. B. C. D. 3
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