Aqueous solutions of ammonia (NH3) and bleach (activeingredient NaOCl) are sold as cleaning fluids, but bottlesof both of them warn: “Never mix ammonia and bleach, astoxic gases may be produced.” One of the toxic gases thatcan be produced is chloroamine, NH2Cl. (a) What is theoxidation number of chlorine in bleach? (b) What is theoxidation number of chlorine in chloramine? (c) Is Cl oxidized,reduced, or neither, upon the conversion of bleachto chloramine? (d) Another toxic gas that can be producedis nitrogen trichloride, NCl3. What is the oxidation numberof N in nitrogen trichloride? (e) Is N oxidized, reduced, or neither, upon the conversion of ammonia to nitrogentrichloride?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Aqueous solutions of ammonia (NH3) and bleach (active
ingredient NaOCl) are sold as cleaning fluids, but bottles
of both of them warn: “Never mix ammonia and bleach, as
toxic gases may be produced.” One of the toxic gases that
can be produced is chloroamine, NH2Cl. (a) What is the
oxidation number of chlorine in bleach? (b) What is the
oxidation number of chlorine in chloramine? (c) Is Cl oxidized,
reduced, or neither, upon the conversion of bleach
to chloramine? (d) Another toxic gas that can be produced
is nitrogen trichloride, NCl3. What is the oxidation number
of N in nitrogen trichloride? (e) Is N oxidized, reduced, or neither, upon the conversion of ammonia to nitrogen
trichloride?

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