APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) 1114 AG} (kJ/mol) S° AH (kJ/mol) (kJ/mol) AG} ану (kJ/mol) Substance U/mol-K) Substance U/mol-K) 96.11 A8CI(s) Ag20(s) AGNO,(s) -127.0 -109.70 Phosphorus (cont.) Plg) Pa(s, red) Pa(s, white) PCly(g) PC() PFs(g) PH3(g) P,O6(s) P,O10(s) POCI(g) -31.05 -11.20 121.3 58.9 24.4 280 -124.4 -33.41 140.9 -17.46 -12.03 22.85 41.08 Sodium 77.3 153.7 -288.07 -319.6 -269.6 311.7 107.7 Na(g) Na(s) Na*(aq) Na*(g) NaBr(aq) NaBr(s) NazCOs(s) NaCl(aq) NaCl(g) NaCl(s) NAHCO,(s) NANO3(ag) NANO3(6) NaOH(aq) NaOH(s) -272.4 217 51.45 -1594.4 -1520.7 300.8 -240.1 -261.9 59.0 5.4 13.4 210.2 609.3 574.3 148.0 -1640.1 -360.6 -364.7 141.00 -2940.1 -2675.2 228.9 -361.4 -349.3 86.82 136.0 1130.9 -407.1 -542.2 -502.5 325 -1047.7 -597.0 -520.9 222 -393.0 115.5 POCI() НРОдаg) -1288.3 -1142.6 158.2 -181.4 -201.3 229.8 -410.9 -384.0 72.33 Potassium -947.7 -851.8 102.1 89.99 61.17 160.2 K(g) K(s) KCI(s) KCIO,(s) KCIO,(ag) KĄCO(s) KNO,(s) KO(s) KO,(s) KO2(s) КОН(6) коНод) -446.2 -372.4 207 64.67 -467.9 --367.0 116.5 435.9 --408.3 82.7 49.8 -469.6 -425.6 -419.2 -391.2 -289.9 143.0 -379.5 64.46 --349.5 --284.9 265.7 -1150.18 -1064.58 155.44 Strontium -592.0 561.9 54.9 -492.70 -363.2 -393.13 132.9 SrO(s) --322.1 94.14 Sr(g) 164.4 110.0 164.6 -284.5 -240.6 122.5 Sulfur S(s, rhombic) S(g) SO(3) SO,(8) So,*"(aq) SOCI;() HSg) HSO,(ag) HSO,() --495.8 -429.8 113.0 31.88 -424.7 -378.9 78.91 162.3 49.7 430.9 -482.4 -440.5 91.6 -296.9 -300.4 248.5 --395.2 -370.4. 256.2 Rubidium -909.3 -744.5 20.1 170.0 76,78 85.8 55.8 Rb(g) Rb(s) RЬCI(:) -245.6 -20.17 -909.3 -33.01 205.6 -430.5 -412.0 92 -744.5 20.1 RBCIO,(s) -392.4 -292.0 152 -814.0 -689.9 156.1 Scandium Titanium 377.8 336.1 174.7 Scg) Sc(s) 468 422 180.3 Ti(g) Ti(s) 34.6 30.76 354.9 221.9 -763.2 -726.8 ПC48) TICL4() TIO2(8) Selenium H,Selg) 29.7 15.9 219.0 -804.2 -728.1 -944.7 -889.4 50.29 Silicon 368.2 323.9 167.8 Vanadium Si(g) Si(s) SIC(S) SICL() SIO2(s, quartz) 18.7 514.2 453.1 182.2 -73.22 --70.85 16.61 V(s) 28.9 239.3 41.84 -640.1 -572.8 Zinc -910.9 -856.5 130.7 95.2. 160.9 Zng Zn(s) ZnClą(s) ZnO(s) 41.63 Silver --415.1 --369.4 111.5 42.55 Ag(s) Ag (aq) -348.0 -318.2 43.9 105.90 77.11 73.93 1113 Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) AH? (kJ/mol) AG (kJ/mol) S° AG (kJ/mol) Şubstance (kJ/mol) U/mol-K) Substance U/mol-K) -569.6 26.8 -205.9 -156.1 MgO(s) Mg(OH)2(s) 108.1 -601.8 CuCla(s) CuO(s) Cuz0(s) - 161.7 -128.3 42.59 -924.7 -833.7 63.24 -170.7 -147.9 92.36 Manganese Mn(g) Mn(s) MnO(s) Fluorine 280.7 238.5 173.6 80.0 61.9 158.7 32.0 F(g) F"(aq) F2lg) HF(g) -362.9 -464.8 -332.6 -278.8 -13.8 -385.2 59.7 -519.6 -541.4 202.7 MnO2(s) 53.14 -268.61 -270.70 173.51 MnO, (ag) --447.2 191.2 AG? AG? (kJ/mol) AH) AH) (kJ/mol) Hydrogen H(g) H*(aq) H*) H2) Mercury Hg(g) Hg() HgCl2(s) Hg2Cl2(s) (kj/mol) (kJ/mol) U/mol-K) Substance 0/mol-K) Substance 217.94 203.26 114.60 60.83 31.76 174.89 52.30 68.11 219.4 77.40 Сан(8) C3H3) C,Ha(8) CH16(8) CH10(1) CHol8) Aluminum 28.32 -84.68 -32.89 229.5 1536.2 1517.0 108.9 -230.1 -184.0 144.5 Al(s) AICly(s) AlzOs(s) -705.6 -630.0 109.3 - 103.85 -23.47 269.9 130.58 -264.9 -210.5 192.5 -1669.8 -1576.S 51.00 -124.73 -15.71 310.0 Iodine Nickel -147.6 --15.0 231.0 106.60 70.16 180.66 429.7 384.5 182.1 I(g) r(aq) Ig) 2(s) HI(g) Ni(g) Ni(s) NIC2(s) NiO(s) Barium 82.9 129.7 269.2 29.9 63.2 -55.19 -51.57 111.3 Ba(s) BaCO(s) BaO(s) 49.0 124.5 172.8 62.25 260.57 -305.3 -259.0 97.65 19.37 -1216.3 -1137.6 112.1 CнHоне) CHОН() CаHоне) CHSOH() CH12O6(s) COg) CO2{8) CH,COОН() -201.2 -161.9 237.6 116.73 -239.7 -211.7 37.99 -553.5 -525.1 70.42 -238.6 --166.23 126.8 25.94 1.30 206.3 Nitrogen N(g) Nzg) NH3(aq) NH3(8) NH, (aq) N2H4(g) NH,CN(6) NH,CI(s) NH,NO3(4) NO(g) NO2(8) N2O(g) NO,(8) NOCI(g) HNO3(aq) HNO,(g) -168.5 282.7 Berylium Be(s). BeO(s) Be(OH)2(s) -235.1 9.44 -277,7 174.76 160.7 Iron 472.7 455.5 153.3 415.5 369.8 180.5 191.50 Felg) Fe(s) Fe2"(aq) Fe"(aq) -608.4 -579.1 13.77 -1273.02 -910.4 212.1 27.15 113.4 -905.8 -817.9 50.21 -110.5 -137.2 197.9 --80.29 -26.50 111.3 -87.86 -84.93 -46.19 - 16.66 192.5 -393.5 -487.0 -394.4 213.6 Bromine -47.69 - 10.54 293.3 -132.5 -79.31 113.4 -392.4 159.8 111.8 82.38 174.9 Br(g) Br"(aq) Br2(g) -341.8 -302.3 117.9 159.4 238.5 FeCh(s) FeCly(s) FeO(s) Fe,O,(s) Fe,O(s) FeS2(s) 95.40 -120.9 -102.8 80.71 Cesium -400 -334 142.3 0.0 30.71 3.14 245.3 76.50 49.53 175.6 Cslg) Cs() -271.9 -255.2 60.75 -314.4 -203.0 94.6 92.07 85.15 152.3 2.09 0.03 -822.16 -1117.1 -740.98 89.96 -365.6 --184.0 151 ABr(g) -36.23 -53.22 198.49 Cs(s) CSCI(s) -1014.2 146.4 90.37 86.71 210.62 --442.8 -414.4 101.2 -160.1 52.92 240.45 Calcium -171.5 33.84 51.84 179.3 145.5 154.8 81.6 103.59 220.0 Ca(g) Ca(s) CaCO,(s, calcite) CaCla(s) CaF2(s) CaO(s) Ca(OH)2(s) CasO,(s) Chlorine Lead 41.4 121.7 105.7 165.2 9.66 98.28 304.3 CI(g) CI"(aq) C2(g) НClag) HC(g) 68.85 Pb(s) РЪВrs(9) РЬСО,) -1207.1 -1128.76 92.88 -167.2 -131.2 56.5 -277.4 -260.7 161 52.6 66.3 264 -795.8 -748.1 104.6 222.96 -206.6 -110.5 146 699.1 -625.5 131.0 -1219.6 -1167.3 68.87 -167.2 -131.2 56.5 --246.9 303.3 -134.3 -73.94 266.4 Pb(NOsh(aq) Pb(NO,)2(s) PbO(s) -421.3 -635.5 -604.17 39.75 -92.30 -95.27 186.69 -451.9 Oxygen Og) Olg) Os(8) OH (aq) -986.2 -898.5 83.4 Chromium -2173 -187.9 68.70 247.5 230.1 161.0 -1434.0 -1321.8 106.7 397.5 352.6 174.2 205.0 Cr(g) Cr(s) CryOs(s) Lithium Carbon 23.6 Li(g) 159.3 126.6 138.8 142.3 163.4 237.6 718.4 672.9 158.0 -1058.1 81.2 -230.0 -157.3 -10.7 Cg) C(s, diamond) C(s, graphite) CCL(8) CC4() CF(g) CH,8) Сн8) -1139.7 29.09. Li(s) Li*(aq) Li"(g) LICI(6) 1.88 2.84 2.43 -241.82 -228.57 188.83 69.91 Н.Os) Н.О() HO28) H2O2(g) -278.5 685.7 Cobalt -273.4 12.2 5.69 -285.83 -136.10 -237.13 -105.48 439 393 179 648.5 133.0 Co(g) Co(s) -106.7 -64.0 309.4 28.4 -408.3 -384.0 59.30 232.9 - 139.3 -68.6 214.4 - 187.8 -120.4 109.6 Copper Cutg) Cu(s) Magnesium Mg(g) Mg(e) MgCl2(s) -679.9 635.1 262.3 148.6 166.3 33.30 Phosphorus P(g) P2(g) -74.8 -50.8 186.3 338.4 298.6 147.1 112.5 32.51 316.4 280.0 163.2 226.77 209.2 200.8 -641.6 -592.1 89.6 144.3 103.7 218.1 1112 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) 1114 Ане APPENDIX
APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) 1114 AG} (kJ/mol) S° AH (kJ/mol) (kJ/mol) AG} ану (kJ/mol) Substance U/mol-K) Substance U/mol-K) 96.11 A8CI(s) Ag20(s) AGNO,(s) -127.0 -109.70 Phosphorus (cont.) Plg) Pa(s, red) Pa(s, white) PCly(g) PC() PFs(g) PH3(g) P,O6(s) P,O10(s) POCI(g) -31.05 -11.20 121.3 58.9 24.4 280 -124.4 -33.41 140.9 -17.46 -12.03 22.85 41.08 Sodium 77.3 153.7 -288.07 -319.6 -269.6 311.7 107.7 Na(g) Na(s) Na*(aq) Na*(g) NaBr(aq) NaBr(s) NazCOs(s) NaCl(aq) NaCl(g) NaCl(s) NAHCO,(s) NANO3(ag) NANO3(6) NaOH(aq) NaOH(s) -272.4 217 51.45 -1594.4 -1520.7 300.8 -240.1 -261.9 59.0 5.4 13.4 210.2 609.3 574.3 148.0 -1640.1 -360.6 -364.7 141.00 -2940.1 -2675.2 228.9 -361.4 -349.3 86.82 136.0 1130.9 -407.1 -542.2 -502.5 325 -1047.7 -597.0 -520.9 222 -393.0 115.5 POCI() НРОдаg) -1288.3 -1142.6 158.2 -181.4 -201.3 229.8 -410.9 -384.0 72.33 Potassium -947.7 -851.8 102.1 89.99 61.17 160.2 K(g) K(s) KCI(s) KCIO,(s) KCIO,(ag) KĄCO(s) KNO,(s) KO(s) KO,(s) KO2(s) КОН(6) коНод) -446.2 -372.4 207 64.67 -467.9 --367.0 116.5 435.9 --408.3 82.7 49.8 -469.6 -425.6 -419.2 -391.2 -289.9 143.0 -379.5 64.46 --349.5 --284.9 265.7 -1150.18 -1064.58 155.44 Strontium -592.0 561.9 54.9 -492.70 -363.2 -393.13 132.9 SrO(s) --322.1 94.14 Sr(g) 164.4 110.0 164.6 -284.5 -240.6 122.5 Sulfur S(s, rhombic) S(g) SO(3) SO,(8) So,*"(aq) SOCI;() HSg) HSO,(ag) HSO,() --495.8 -429.8 113.0 31.88 -424.7 -378.9 78.91 162.3 49.7 430.9 -482.4 -440.5 91.6 -296.9 -300.4 248.5 --395.2 -370.4. 256.2 Rubidium -909.3 -744.5 20.1 170.0 76,78 85.8 55.8 Rb(g) Rb(s) RЬCI(:) -245.6 -20.17 -909.3 -33.01 205.6 -430.5 -412.0 92 -744.5 20.1 RBCIO,(s) -392.4 -292.0 152 -814.0 -689.9 156.1 Scandium Titanium 377.8 336.1 174.7 Scg) Sc(s) 468 422 180.3 Ti(g) Ti(s) 34.6 30.76 354.9 221.9 -763.2 -726.8 ПC48) TICL4() TIO2(8) Selenium H,Selg) 29.7 15.9 219.0 -804.2 -728.1 -944.7 -889.4 50.29 Silicon 368.2 323.9 167.8 Vanadium Si(g) Si(s) SIC(S) SICL() SIO2(s, quartz) 18.7 514.2 453.1 182.2 -73.22 --70.85 16.61 V(s) 28.9 239.3 41.84 -640.1 -572.8 Zinc -910.9 -856.5 130.7 95.2. 160.9 Zng Zn(s) ZnClą(s) ZnO(s) 41.63 Silver --415.1 --369.4 111.5 42.55 Ag(s) Ag (aq) -348.0 -318.2 43.9 105.90 77.11 73.93 1113 Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) AH? (kJ/mol) AG (kJ/mol) S° AG (kJ/mol) Şubstance (kJ/mol) U/mol-K) Substance U/mol-K) -569.6 26.8 -205.9 -156.1 MgO(s) Mg(OH)2(s) 108.1 -601.8 CuCla(s) CuO(s) Cuz0(s) - 161.7 -128.3 42.59 -924.7 -833.7 63.24 -170.7 -147.9 92.36 Manganese Mn(g) Mn(s) MnO(s) Fluorine 280.7 238.5 173.6 80.0 61.9 158.7 32.0 F(g) F"(aq) F2lg) HF(g) -362.9 -464.8 -332.6 -278.8 -13.8 -385.2 59.7 -519.6 -541.4 202.7 MnO2(s) 53.14 -268.61 -270.70 173.51 MnO, (ag) --447.2 191.2 AG? AG? (kJ/mol) AH) AH) (kJ/mol) Hydrogen H(g) H*(aq) H*) H2) Mercury Hg(g) Hg() HgCl2(s) Hg2Cl2(s) (kj/mol) (kJ/mol) U/mol-K) Substance 0/mol-K) Substance 217.94 203.26 114.60 60.83 31.76 174.89 52.30 68.11 219.4 77.40 Сан(8) C3H3) C,Ha(8) CH16(8) CH10(1) CHol8) Aluminum 28.32 -84.68 -32.89 229.5 1536.2 1517.0 108.9 -230.1 -184.0 144.5 Al(s) AICly(s) AlzOs(s) -705.6 -630.0 109.3 - 103.85 -23.47 269.9 130.58 -264.9 -210.5 192.5 -1669.8 -1576.S 51.00 -124.73 -15.71 310.0 Iodine Nickel -147.6 --15.0 231.0 106.60 70.16 180.66 429.7 384.5 182.1 I(g) r(aq) Ig) 2(s) HI(g) Ni(g) Ni(s) NIC2(s) NiO(s) Barium 82.9 129.7 269.2 29.9 63.2 -55.19 -51.57 111.3 Ba(s) BaCO(s) BaO(s) 49.0 124.5 172.8 62.25 260.57 -305.3 -259.0 97.65 19.37 -1216.3 -1137.6 112.1 CнHоне) CHОН() CаHоне) CHSOH() CH12O6(s) COg) CO2{8) CH,COОН() -201.2 -161.9 237.6 116.73 -239.7 -211.7 37.99 -553.5 -525.1 70.42 -238.6 --166.23 126.8 25.94 1.30 206.3 Nitrogen N(g) Nzg) NH3(aq) NH3(8) NH, (aq) N2H4(g) NH,CN(6) NH,CI(s) NH,NO3(4) NO(g) NO2(8) N2O(g) NO,(8) NOCI(g) HNO3(aq) HNO,(g) -168.5 282.7 Berylium Be(s). BeO(s) Be(OH)2(s) -235.1 9.44 -277,7 174.76 160.7 Iron 472.7 455.5 153.3 415.5 369.8 180.5 191.50 Felg) Fe(s) Fe2"(aq) Fe"(aq) -608.4 -579.1 13.77 -1273.02 -910.4 212.1 27.15 113.4 -905.8 -817.9 50.21 -110.5 -137.2 197.9 --80.29 -26.50 111.3 -87.86 -84.93 -46.19 - 16.66 192.5 -393.5 -487.0 -394.4 213.6 Bromine -47.69 - 10.54 293.3 -132.5 -79.31 113.4 -392.4 159.8 111.8 82.38 174.9 Br(g) Br"(aq) Br2(g) -341.8 -302.3 117.9 159.4 238.5 FeCh(s) FeCly(s) FeO(s) Fe,O,(s) Fe,O(s) FeS2(s) 95.40 -120.9 -102.8 80.71 Cesium -400 -334 142.3 0.0 30.71 3.14 245.3 76.50 49.53 175.6 Cslg) Cs() -271.9 -255.2 60.75 -314.4 -203.0 94.6 92.07 85.15 152.3 2.09 0.03 -822.16 -1117.1 -740.98 89.96 -365.6 --184.0 151 ABr(g) -36.23 -53.22 198.49 Cs(s) CSCI(s) -1014.2 146.4 90.37 86.71 210.62 --442.8 -414.4 101.2 -160.1 52.92 240.45 Calcium -171.5 33.84 51.84 179.3 145.5 154.8 81.6 103.59 220.0 Ca(g) Ca(s) CaCO,(s, calcite) CaCla(s) CaF2(s) CaO(s) Ca(OH)2(s) CasO,(s) Chlorine Lead 41.4 121.7 105.7 165.2 9.66 98.28 304.3 CI(g) CI"(aq) C2(g) НClag) HC(g) 68.85 Pb(s) РЪВrs(9) РЬСО,) -1207.1 -1128.76 92.88 -167.2 -131.2 56.5 -277.4 -260.7 161 52.6 66.3 264 -795.8 -748.1 104.6 222.96 -206.6 -110.5 146 699.1 -625.5 131.0 -1219.6 -1167.3 68.87 -167.2 -131.2 56.5 --246.9 303.3 -134.3 -73.94 266.4 Pb(NOsh(aq) Pb(NO,)2(s) PbO(s) -421.3 -635.5 -604.17 39.75 -92.30 -95.27 186.69 -451.9 Oxygen Og) Olg) Os(8) OH (aq) -986.2 -898.5 83.4 Chromium -2173 -187.9 68.70 247.5 230.1 161.0 -1434.0 -1321.8 106.7 397.5 352.6 174.2 205.0 Cr(g) Cr(s) CryOs(s) Lithium Carbon 23.6 Li(g) 159.3 126.6 138.8 142.3 163.4 237.6 718.4 672.9 158.0 -1058.1 81.2 -230.0 -157.3 -10.7 Cg) C(s, diamond) C(s, graphite) CCL(8) CC4() CF(g) CH,8) Сн8) -1139.7 29.09. Li(s) Li*(aq) Li"(g) LICI(6) 1.88 2.84 2.43 -241.82 -228.57 188.83 69.91 Н.Os) Н.О() HO28) H2O2(g) -278.5 685.7 Cobalt -273.4 12.2 5.69 -285.83 -136.10 -237.13 -105.48 439 393 179 648.5 133.0 Co(g) Co(s) -106.7 -64.0 309.4 28.4 -408.3 -384.0 59.30 232.9 - 139.3 -68.6 214.4 - 187.8 -120.4 109.6 Copper Cutg) Cu(s) Magnesium Mg(g) Mg(e) MgCl2(s) -679.9 635.1 262.3 148.6 166.3 33.30 Phosphorus P(g) P2(g) -74.8 -50.8 186.3 338.4 298.6 147.1 112.5 32.51 316.4 280.0 163.2 226.77 209.2 200.8 -641.6 -592.1 89.6 144.3 103.7 218.1 1112 APPENDIX C Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C) 1114 Ане APPENDIX
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Valence Bond Theory Vbt
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Question
Using appendix C values, calculate the delta H
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Transcribed Image Text:APPENDIX C
Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C)
1114
AG}
(kJ/mol)
S°
AH
(kJ/mol) (kJ/mol)
AG}
ану
(kJ/mol)
Substance
U/mol-K)
Substance
U/mol-K)
96.11
A8CI(s)
Ag20(s)
AGNO,(s)
-127.0
-109.70
Phosphorus (cont.)
Plg)
Pa(s, red)
Pa(s, white)
PCly(g)
PC()
PFs(g)
PH3(g)
P,O6(s)
P,O10(s)
POCI(g)
-31.05
-11.20
121.3
58.9
24.4
280
-124.4
-33.41
140.9
-17.46
-12.03
22.85
41.08
Sodium
77.3
153.7
-288.07
-319.6
-269.6
311.7
107.7
Na(g)
Na(s)
Na*(aq)
Na*(g)
NaBr(aq)
NaBr(s)
NazCOs(s)
NaCl(aq)
NaCl(g)
NaCl(s)
NAHCO,(s)
NANO3(ag)
NANO3(6)
NaOH(aq)
NaOH(s)
-272.4
217
51.45
-1594.4
-1520.7
300.8
-240.1
-261.9
59.0
5.4
13.4
210.2
609.3
574.3
148.0
-1640.1
-360.6
-364.7
141.00
-2940.1
-2675.2
228.9
-361.4
-349.3
86.82
136.0
1130.9
-407.1
-542.2
-502.5
325
-1047.7
-597.0
-520.9
222
-393.0
115.5
POCI()
НРОдаg)
-1288.3
-1142.6
158.2
-181.4
-201.3
229.8
-410.9
-384.0
72.33
Potassium
-947.7
-851.8
102.1
89.99
61.17
160.2
K(g)
K(s)
KCI(s)
KCIO,(s)
KCIO,(ag)
KĄCO(s)
KNO,(s)
KO(s)
KO,(s)
KO2(s)
КОН(6)
коНод)
-446.2
-372.4
207
64.67
-467.9
--367.0
116.5
435.9
--408.3
82.7
49.8
-469.6
-425.6
-419.2
-391.2
-289.9
143.0
-379.5
64.46
--349.5
--284.9
265.7
-1150.18
-1064.58
155.44
Strontium
-592.0
561.9
54.9
-492.70
-363.2
-393.13
132.9
SrO(s)
--322.1
94.14
Sr(g)
164.4
110.0
164.6
-284.5
-240.6
122.5
Sulfur
S(s, rhombic)
S(g)
SO(3)
SO,(8)
So,*"(aq)
SOCI;()
HSg)
HSO,(ag)
HSO,()
--495.8
-429.8
113.0
31.88
-424.7
-378.9
78.91
162.3
49.7
430.9
-482.4
-440.5
91.6
-296.9
-300.4
248.5
--395.2
-370.4.
256.2
Rubidium
-909.3
-744.5
20.1
170.0
76,78
85.8
55.8
Rb(g)
Rb(s)
RЬCI(:)
-245.6
-20.17
-909.3
-33.01
205.6
-430.5
-412.0
92
-744.5
20.1
RBCIO,(s)
-392.4
-292.0
152
-814.0
-689.9
156.1
Scandium
Titanium
377.8
336.1
174.7
Scg)
Sc(s)
468
422
180.3
Ti(g)
Ti(s)
34.6
30.76
354.9
221.9
-763.2
-726.8
ПC48)
TICL4()
TIO2(8)
Selenium
H,Selg)
29.7
15.9
219.0
-804.2
-728.1
-944.7
-889.4
50.29
Silicon
368.2
323.9
167.8
Vanadium
Si(g)
Si(s)
SIC(S)
SICL()
SIO2(s, quartz)
18.7
514.2
453.1
182.2
-73.22
--70.85
16.61
V(s)
28.9
239.3
41.84
-640.1
-572.8
Zinc
-910.9
-856.5
130.7
95.2.
160.9
Zng
Zn(s)
ZnClą(s)
ZnO(s)
41.63
Silver
--415.1
--369.4
111.5
42.55
Ag(s)
Ag (aq)
-348.0
-318.2
43.9
105.90
77.11
73.93
Transcribed Image Text:1113
Thermodynamic Quantities
for Selected Substances at
298.15 K (25 °C)
APPENDIX C
Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C)
AH?
(kJ/mol)
AG
(kJ/mol)
S°
AG
(kJ/mol)
Şubstance
(kJ/mol)
U/mol-K)
Substance
U/mol-K)
-569.6
26.8
-205.9
-156.1
MgO(s)
Mg(OH)2(s)
108.1
-601.8
CuCla(s)
CuO(s)
Cuz0(s)
- 161.7
-128.3
42.59
-924.7
-833.7
63.24
-170.7
-147.9
92.36
Manganese
Mn(g)
Mn(s)
MnO(s)
Fluorine
280.7
238.5
173.6
80.0
61.9
158.7
32.0
F(g)
F"(aq)
F2lg)
HF(g)
-362.9
-464.8
-332.6
-278.8
-13.8
-385.2
59.7
-519.6
-541.4
202.7
MnO2(s)
53.14
-268.61
-270.70
173.51
MnO, (ag)
--447.2
191.2
AG?
AG?
(kJ/mol)
AH)
AH)
(kJ/mol)
Hydrogen
H(g)
H*(aq)
H*)
H2)
Mercury
Hg(g)
Hg()
HgCl2(s)
Hg2Cl2(s)
(kj/mol)
(kJ/mol)
U/mol-K)
Substance
0/mol-K)
Substance
217.94
203.26
114.60
60.83
31.76
174.89
52.30
68.11
219.4
77.40
Сан(8)
C3H3)
C,Ha(8)
CH16(8)
CH10(1)
CHol8)
Aluminum
28.32
-84.68
-32.89
229.5
1536.2
1517.0
108.9
-230.1
-184.0
144.5
Al(s)
AICly(s)
AlzOs(s)
-705.6
-630.0
109.3
- 103.85
-23.47
269.9
130.58
-264.9
-210.5
192.5
-1669.8
-1576.S
51.00
-124.73
-15.71
310.0
Iodine
Nickel
-147.6
--15.0
231.0
106.60
70.16
180.66
429.7
384.5
182.1
I(g)
r(aq)
Ig)
2(s)
HI(g)
Ni(g)
Ni(s)
NIC2(s)
NiO(s)
Barium
82.9
129.7
269.2
29.9
63.2
-55.19
-51.57
111.3
Ba(s)
BaCO(s)
BaO(s)
49.0
124.5
172.8
62.25
260.57
-305.3
-259.0
97.65
19.37
-1216.3
-1137.6
112.1
CнHоне)
CHОН()
CаHоне)
CHSOH()
CH12O6(s)
COg)
CO2{8)
CH,COОН()
-201.2
-161.9
237.6
116.73
-239.7
-211.7
37.99
-553.5
-525.1
70.42
-238.6
--166.23
126.8
25.94
1.30
206.3
Nitrogen
N(g)
Nzg)
NH3(aq)
NH3(8)
NH, (aq)
N2H4(g)
NH,CN(6)
NH,CI(s)
NH,NO3(4)
NO(g)
NO2(8)
N2O(g)
NO,(8)
NOCI(g)
HNO3(aq)
HNO,(g)
-168.5
282.7
Berylium
Be(s).
BeO(s)
Be(OH)2(s)
-235.1
9.44
-277,7
174.76
160.7
Iron
472.7
455.5
153.3
415.5
369.8
180.5
191.50
Felg)
Fe(s)
Fe2"(aq)
Fe"(aq)
-608.4
-579.1
13.77
-1273.02
-910.4
212.1
27.15
113.4
-905.8
-817.9
50.21
-110.5
-137.2
197.9
--80.29
-26.50
111.3
-87.86
-84.93
-46.19
- 16.66
192.5
-393.5
-487.0
-394.4
213.6
Bromine
-47.69
- 10.54
293.3
-132.5
-79.31
113.4
-392.4
159.8
111.8
82.38
174.9
Br(g)
Br"(aq)
Br2(g)
-341.8
-302.3
117.9
159.4
238.5
FeCh(s)
FeCly(s)
FeO(s)
Fe,O,(s)
Fe,O(s)
FeS2(s)
95.40
-120.9
-102.8
80.71
Cesium
-400
-334
142.3
0.0
30.71
3.14
245.3
76.50
49.53
175.6
Cslg)
Cs()
-271.9
-255.2
60.75
-314.4
-203.0
94.6
92.07
85.15
152.3
2.09
0.03
-822.16
-1117.1
-740.98
89.96
-365.6
--184.0
151
ABr(g)
-36.23
-53.22
198.49
Cs(s)
CSCI(s)
-1014.2
146.4
90.37
86.71
210.62
--442.8
-414.4
101.2
-160.1
52.92
240.45
Calcium
-171.5
33.84
51.84
179.3
145.5
154.8
81.6
103.59
220.0
Ca(g)
Ca(s)
CaCO,(s, calcite)
CaCla(s)
CaF2(s)
CaO(s)
Ca(OH)2(s)
CasO,(s)
Chlorine
Lead
41.4
121.7
105.7
165.2
9.66
98.28
304.3
CI(g)
CI"(aq)
C2(g)
НClag)
HC(g)
68.85
Pb(s)
РЪВrs(9)
РЬСО,)
-1207.1
-1128.76
92.88
-167.2
-131.2
56.5
-277.4
-260.7
161
52.6
66.3
264
-795.8
-748.1
104.6
222.96
-206.6
-110.5
146
699.1
-625.5
131.0
-1219.6
-1167.3
68.87
-167.2
-131.2
56.5
--246.9
303.3
-134.3
-73.94
266.4
Pb(NOsh(aq)
Pb(NO,)2(s)
PbO(s)
-421.3
-635.5
-604.17
39.75
-92.30
-95.27
186.69
-451.9
Oxygen
Og)
Olg)
Os(8)
OH (aq)
-986.2
-898.5
83.4
Chromium
-2173
-187.9
68.70
247.5
230.1
161.0
-1434.0
-1321.8
106.7
397.5
352.6
174.2
205.0
Cr(g)
Cr(s)
CryOs(s)
Lithium
Carbon
23.6
Li(g)
159.3
126.6
138.8
142.3
163.4
237.6
718.4
672.9
158.0
-1058.1
81.2
-230.0
-157.3
-10.7
Cg)
C(s, diamond)
C(s, graphite)
CCL(8)
CC4()
CF(g)
CH,8)
Сн8)
-1139.7
29.09.
Li(s)
Li*(aq)
Li"(g)
LICI(6)
1.88
2.84
2.43
-241.82
-228.57
188.83
69.91
Н.Os)
Н.О()
HO28)
H2O2(g)
-278.5
685.7
Cobalt
-273.4
12.2
5.69
-285.83
-136.10
-237.13
-105.48
439
393
179
648.5
133.0
Co(g)
Co(s)
-106.7
-64.0
309.4
28.4
-408.3
-384.0
59.30
232.9
- 139.3
-68.6
214.4
- 187.8
-120.4
109.6
Copper
Cutg)
Cu(s)
Magnesium
Mg(g)
Mg(e)
MgCl2(s)
-679.9
635.1
262.3
148.6
166.3
33.30
Phosphorus
P(g)
P2(g)
-74.8
-50.8
186.3
338.4
298.6
147.1
112.5
32.51
316.4
280.0
163.2
226.77
209.2
200.8
-641.6
-592.1
89.6
144.3
103.7
218.1
1112
APPENDIX C
Thermodynamic Quantities for Selected Substances at 298.15 K (25 °C)
1114
Ане
APPENDIX
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