Answer the following questions about preparing the same buffer solution using three different methods. All three buffers are to have a pH of 9.00. Be sure to show your logic clearly and with all steps in the calculation.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Answer the following questions about preparing the same buffer solution using three different methods. All three buffers are to have a pH of 9.00. Be sure to show your logic clearly and with all steps in the calculation.

a. Given two separate solutions, 0.100 M ammonia and 0.100 M ammonium chloride, calculate the volume of each solution required to form 60.0 mL of a mixture that has the desired pH. 

b. Calculate the amount of solid NH4Cl to add to 60.0 mL of 0.100 M ammonia to form a mixture that has the desired pH. Assume no volume change in the solution. Hint: Use the same buffer ratio that you used in (a).

c. Calculate the volume of 0.100 M HCl that is required to react with 50.0 mL of 0.100 M ammonia to form a mixture that has the desired pH. Hint: think of this as a titration problem. Unlike (a) and (b), there IS a reaction between acid and base.

 

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