Answer ALL parts of this question. (a) Explain the following observations in first ionisation energies (IE1₁). (i) There is a large decrease in IE1 between He and LI, Ne and Na and, Ar and K. (ii) (iii) IE₁ is lower for Al than Mg. IE₁ is lower than IE2. (b) Explain the trend in effective nuclear charge (Z) going from left to right across periods in the periodic table and with reference to Z", rationalise why the ionic radii of the following anions decrease in the order shown: As> Se²-> Br.

Chemistry for Engineering Students
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Chapter6: The Periodic Table And Atomic Structure
Section: Chapter Questions
Problem 6.82PAE: 6.82 A particular element has the following values for its first four ionization energies: 900,...
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Answer ALL parts of this question.
(a) Explain the following observations in first ionisation energies (IE1).
(i)
There is a large decrease in IE₁ between He and LI, Ne and Na
and, Ar and K.
IE: is lower for Al than Mg.
IE₁ is lower than IE2.
(ii)
(iii)
(b) Explain the trend in effective nuclear charge (Z) going from left to right
across periods in the periodic table and with reference to Z*, rationalise
why the ionic radii of the following anions decrease in the order shown:
As > Se²> Br.
Transcribed Image Text:Answer ALL parts of this question. (a) Explain the following observations in first ionisation energies (IE1). (i) There is a large decrease in IE₁ between He and LI, Ne and Na and, Ar and K. IE: is lower for Al than Mg. IE₁ is lower than IE2. (ii) (iii) (b) Explain the trend in effective nuclear charge (Z) going from left to right across periods in the periodic table and with reference to Z*, rationalise why the ionic radii of the following anions decrease in the order shown: As > Se²> Br.
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