ANALYSIS FOR IONS Name __________________________ Section _________ Date _______________ Determination of Cation and Anion of Unknown Salt Although you are most familiar with table salt, which is the salt used in cooking and seasoning of foods, the family of "salts" has many members. Most are found in nature, such as the chlorides of sodium, potassium and calcium, but all can be formed in the laboratory as a product of a neutralization reaction, that is a reaction between an acid and a base in water. The formation of table salt, NaCl, results by reacting hydrochloric acid and sodium hydroxide as represented by the following equation: HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l) Your unknown salt contains only one cation. It may be any one of the following four: Na+, K+, Ca2+ or Fe3+ Your unknown salt contains only one anion. It may be any one of the following four: CO32-, Cl-, SO42- or PO43- Thus, there are many possible combinations, and you must determine which salt is the unknown given to you. Testing for the Cation of the Unknown Salt You should observe only one positive test for the cation in your unknown. a) In a flame tests for Na+, K+, Ca2+, the color of the flame is bright yellow, violet, or orange-red, respectively. However, the orange-red flame for calcium may not be very prominent. Thus, calcium will require a confirmatory test, and will form a white precipitate when treated with ammonium oxalate (NH4)2C2O4. When a salt containing Fe3+ is treated with potassium thiocyanate (KSCN) solution, a blood-red colored solution will form. By now you should have determined which cation is present in your Testing for the Anion of the Unknown Salt You should observe only one positive test for the anion in your unknown. Any salt containing CO32- ions will react promptly with an acid (e.g., HCl(aq)) to form carbon dioxide gas, which will foam and bubble up in the test tube. If the unknown solution immediately forms a white precipitate when mixed with silver nitrate (AgNO3), and if the precipitate is permanent (that is, it cannot be dissolved in nitric acid), then it proves that chloride ion (Cl-) is present. Sulfate ions will form a permanent white precipitate when treated with barium chloride (BaCl2(aq)) and nitric acid (HNO3). The proof that PO43- ions are present is the formation of a bright yellow precipitate when a phosphate salt is treated with ammonium molybdate, ((NH4)2MoO4) and nitric acid (HNO3). A positive result would indicate which anion? By now you should have determined what anion is present in your 3. Conclusion The report form contains observations that were made by one of your classmates. Based on these observations, fill in the blanks to indicate if the ions are present or absent. From the overall set of observations decide which of the salts is your unknown by giving its cation and anion, formula, and name at the end of the report sheet. Deliverable Complete the report by answering the questions on page 5. Submit pages 3,4, and 5 to your instructor on the due date. PART B: ANION TESTS OPERATION OBSERVATION CONCLUSIONSection 4: Test for Carbonate (CO32-) ions 6 M HCl with Na2CO3 Bubbling 6 M HCl with NaCl Clear solution 6 M HCl with Na2SO4 Clear solution 6 M HCl with Na3PO4 Clear solution 6 M HCl with unknown Clear solution Section 5: Test for Chloride (Cl-) ions After HNO3 addedAgNO3 with Na2CO3 / HNO3 White precipitate Clear solution AgNO3 with NaCl / HNO3 White precipitate Precipitate stays AgNO3 with Na2SO4 / HNO3 Clear solution Clear solution AgNO3 with Na3PO4 / HNO3 White precipitate Clear solution AgNO3 with unknown / HNO3 White precipitate Clear solution Section 6: Test for Sulfate (SO42-) ions After HNO3 addedBaCl2 with Na2CO3 / HNO3 White precipitate Clear solution BaCl2 with NaCl / HNO3 Clear solution Clear solution BaCl2 with Na2SO4 / HNO3 White precipitate Precipitate stays BaCl2 with Na3PO4 / HNO3 White precipitate Clear solution BaCl2 with unknown / HNO3 White precipitate Precipitate stays Section 7: Test for Phosphate (PO43-) ions(NH4)2MoO4 with Na2CO3 Clear solution (NH4)2MoO4 with NaCl Clear solution (NH4)2MoO4 with Na2SO4 Clear solution (NH4)2MoO4 with Na3PO4 Yellow precipitate (NH4)2MoO4 with unknown Clear solution The unknown anion is _______________ Summary from Observations and Conclusions in PARTS A and B: Unknown Sample # ____XYZ______ Cation __________ Anion ___________Unknown Name __________________________ Unknown Formula______________

ANALYSIS FOR IONS Name ______________________ Section _ Date ___ Determination of Cation and Anion of Unknown Salt Although you are most familiar with table salt, which is the salt used in cooking and seasoning of foods, the family of "salts" has many members. Most are found in nature, such as the chlorides of sodium, potassium and calcium, but all can be formed in the laboratory as a product of a neutralization reaction, that is a reaction between an acid and a base in water. The formation of table salt, NaCl, results by reacting hydrochloric acid and sodium hydroxide as represented by the following equation: HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l) Your unknown salt contains only one cation. It may be any one of the following four: Na+, K+, Ca2+ or Fe3+ Your unknown salt contains only one anion. It may be any one of the following four: CO32-, Cl-, SO42- or PO43- Thus, there are many possible combinations, and you must determine which salt is the unknown given to you. Testing for the Cation of the Unknown Salt You should observe only one positive test for the cation in your unknown. a) In a flame tests for Na+, K+, Ca2+, the color of the flame is bright yellow, violet, or orange-red, respectively. However, the orange-red flame for calcium may not be very prominent. Thus, calcium will require a confirmatory test, and will form a white precipitate when treated with ammonium oxalate (NH4)2C2O4. When a salt containing Fe3+ is treated with potassium thiocyanate (KSCN) solution, a blood-red colored solution will form. By now you should have determined which cation is present in your Testing for the Anion of the Unknown Salt You should observe only one positive test for the anion in your unknown. Any salt containing CO32- ions will react promptly with an acid (e.g., HCl(aq)) to form carbon dioxide gas, which will foam and bubble up in the test tube. If the unknown solution immediately forms a white precipitate when mixed with silver nitrate (AgNO3), and if the precipitate is permanent (that is, it cannot be dissolved in nitric acid), then it proves that chloride ion (Cl-) is present. Sulfate ions will form a permanent white precipitate when treated with barium chloride (BaCl2(aq)) and nitric acid (HNO3). The proof that PO43- ions are present is the formation of a bright yellow precipitate when a phosphate salt is treated with ammonium molybdate, ((NH4)2MoO4) and nitric acid (HNO3). A positive result would indicate which anion? By now you should have determined what anion is present in your 3. Conclusion The report form contains observations that were made by one of your classmates. Based on these observations, fill in the blanks to indicate if the ions are present or absent. From the overall set of observations decide which of the salts is your unknown by giving its cation and anion, formula, and name at the end of the report sheet. Deliverable Complete the report by answering the questions on page 5. Submit pages 3,4, and 5 to your instructor on the due date. PART B: ANION TESTS OPERATION OBSERVATION CONCLUSIONSection 4: Test for Carbonate (CO32-) ions 6 M HCl with Na2CO3 Bubbling 6 M HCl with NaCl Clear solution 6 M HCl with Na2SO4 Clear solution 6 M HCl with Na3PO4 Clear solution 6 M HCl with unknown Clear solution Section 5: Test for Chloride (Cl-) ions After HNO3 addedAgNO3 with Na2CO3 / HNO3 White precipitate Clear solution AgNO3 with NaCl / HNO3 White precipitate Precipitate stays AgNO3 with Na2SO4 / HNO3 Clear solution Clear solution AgNO3 with Na3PO4 / HNO3 White precipitate Clear solution AgNO3 with unknown / HNO3 White precipitate Clear solution Section 6: Test for Sulfate (SO42-) ions After HNO3 addedBaCl2 with Na2CO3 / HNO3 White precipitate Clear solution BaCl2 with NaCl / HNO3 Clear solution Clear solution BaCl2 with Na2SO4 / HNO3 White precipitate Precipitate stays BaCl2 with Na3PO4 / HNO3 White precipitate Clear solution BaCl2 with unknown / HNO3 White precipitate Precipitate stays Section 7: Test for Phosphate (PO43-) ions(NH4)2MoO4 with Na2CO3 Clear solution (NH4)2MoO4 with NaCl Clear solution (NH4)2MoO4 with Na2SO4 Clear solution (NH4)2MoO4 with Na3PO4 Yellow precipitate (NH4)2MoO4 with unknown Clear solution The unknown anion is _ Summary from Observations and Conclusions in PARTS A and B: Unknown Sample # XYZ Cation Anion _Unknown Name ________ Unknown Formula

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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ANALYSIS FOR IONS

Name __________________________ Section _________ Date _______________

Determination of Cation and Anion of Unknown Salt

Although you are most familiar with table salt, which is the salt used in cooking and seasoning of foods, the family of "salts" has many members. Most are found in nature, such as the chlorides of sodium, potassium and calcium, but all can be formed in the laboratory as a product of a neutralization reaction, that is a reaction between an acid and a base in water. The formation of table salt, NaCl, results by reacting hydrochloric acid and sodium hydroxide as represented by the following equation:

HCl_(aq) + NaOH_(aq) → NaCl_(aq) + H₂O_(l)

Your unknown salt contains only one cation. It may be any one of the following four:

Na⁺, K⁺, Ca²⁺ or Fe³⁺

Your unknown salt contains only one anion. It may be any one of the following four:

CO₃^2-, Cl^-, SO₄^2- or PO₄^3-

Thus, there are many possible combinations, and you must determine which salt is the unknown given to you.

Testing for the Cation of the Unknown Salt

You should observe only one positive test for the cation in your unknown.

a) In a flame tests for Na⁺, K⁺, Ca²⁺, the color of the flame is bright yellow, violet, or orange-red, respectively. However, the orange-red flame for calcium may not be very prominent.
Thus, calcium will require a confirmatory test, and will form a white precipitate when treated with ammonium oxalate (NH₄)₂C₂O₄.
When a salt containing Fe³⁺is treated with potassium thiocyanate (KSCN) solution, a blood-red colored solution will form.
By now you should have determined which cation is present in your

Testing for the Anion of the Unknown Salt

You should observe only one positive test for the anion in your unknown.

Any salt containing CO₃^2-ions will react promptly with an acid (e.g., HCl_(aq)) to form carbon dioxide gas, which will foam and bubble up in the test tube.
If the unknown solution immediately forms a white precipitate when mixed with silver nitrate (AgNO₃), and if the precipitate is permanent (that is, it cannot be dissolved in nitric acid), then it proves that chloride ion (Cl^-) is present.
Sulfate ions will form a permanent white precipitate when treated with barium chloride (BaCl_2(aq)) and nitric acid (HNO₃).
The proof that PO₄^3-ions are present is the formation of a bright yellow precipitate when a phosphate salt is treated with ammonium molybdate, ((NH₄)₂MoO₄) and nitric acid (HNO₃). A positive result would indicate which anion?
By now you should have determined what anion is present in your
3. Conclusion

The report form contains observations that were made by one of your classmates. Based on these observations, fill in the blanks to indicate if the ions are present or absent. From the overall set of observations decide which of the salts is your unknown by giving its cation and anion, formula, and name at the end of the report sheet.

Deliverable

Complete the report by answering the questions on page 5. Submit pages 3,4, and 5 to your instructor on the due date.

PART B: ANION TESTS

OPERATION OBSERVATION CONCLUSION
Section 4: Test for Carbonate (CO32-) ions
6 M HCl with Na2CO3 Bubbling
6 M HCl with NaCl Clear solution
6 M HCl with Na2SO4 Clear solution
6 M HCl with Na3PO4 Clear solution
6 M HCl with unknown Clear solution

Section 5: Test for Chloride (Cl-) ions After HNO3 added
AgNO3 with Na2CO3 / HNO3 White precipitate Clear solution
AgNO3 with NaCl / HNO3 White precipitate Precipitate stays
AgNO3 with Na2SO4 / HNO3 Clear solution Clear solution
AgNO3 with Na3PO4 / HNO3 White precipitate Clear solution
AgNO3 with unknown / HNO3 White precipitate Clear solution

Section 6: Test for Sulfate (SO42-) ions After HNO3 added
BaCl2 with Na2CO3 / HNO3 White precipitate Clear solution
BaCl2 with NaCl / HNO3 Clear solution Clear solution
BaCl2 with Na2SO4 / HNO3 White precipitate Precipitate stays
BaCl2 with Na3PO4 / HNO3 White precipitate Clear solution
BaCl2 with unknown / HNO3 White precipitate Precipitate stays

Section 7: Test for Phosphate (PO43-) ions
(NH4)2MoO4 with Na2CO3 Clear solution
(NH4)2MoO4 with NaCl Clear solution
(NH4)2MoO4 with Na2SO4 Clear solution
(NH4)2MoO4 with Na3PO4 Yellow precipitate
(NH4)2MoO4 with unknown Clear solution

The unknown anion is _______________

Summary from Observations and Conclusions in PARTS A and B:
Unknown Sample # ____XYZ______ Cation __________ Anion ___________

Unknown Name __________________________ Unknown Formula______________

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