An unknown gas, D, reacts with fluorine gas to form the compound DF4(g), as represented by the following equation: D(g)+2 F2(g)→DF4(g). A series of experimental trials were performed at 600° to determine the rate law expression for the reaction. Data from the trials are shown below. Initial PD (torr) Initial PF2 (torr) Initial Rate of Appearance of DF4(g) (torr/min) Trial 1 3000 3000 2.50x10-2 Trial 2 Trial 3 6000 3000 5.0x10-2 3000 6000 10.0x10-2 Fluorine can also react with another gas, E(g), according to the following equation: E(g)+2 F2(g)>EF4(g) AHo=-150 kJ/molx0 g) The student claims that the D-F bond energy is less than the E-F bond energy. Do you agree or disagree? Justify your answer. While investigating the properties of other diatomic molecules, the student finds the following diagram, which shows the potential energy of two iodine atoms versus the distance between their nuclei. The student also finds that the l-I bond energy is slightly less than the F-F bond energy. The student incorrectly sketches the potential energy curve for 2 fluorine atoms, shown by the dotted line. 200- 100+ 主一 200 i 600 700 0- 100 300i 400 500 800 -100+ -200- Internuclear Distance (pm) h) Explain the error with the student's sketch for F2(g). Potential Energy (kJ/mol)
An unknown gas, D, reacts with fluorine gas to form the compound DF4(g), as represented by the following equation: D(g)+2 F2(g)→DF4(g). A series of experimental trials were performed at 600° to determine the rate law expression for the reaction. Data from the trials are shown below. Initial PD (torr) Initial PF2 (torr) Initial Rate of Appearance of DF4(g) (torr/min) Trial 1 3000 3000 2.50x10-2 Trial 2 Trial 3 6000 3000 5.0x10-2 3000 6000 10.0x10-2 Fluorine can also react with another gas, E(g), according to the following equation: E(g)+2 F2(g)>EF4(g) AHo=-150 kJ/molx0 g) The student claims that the D-F bond energy is less than the E-F bond energy. Do you agree or disagree? Justify your answer. While investigating the properties of other diatomic molecules, the student finds the following diagram, which shows the potential energy of two iodine atoms versus the distance between their nuclei. The student also finds that the l-I bond energy is slightly less than the F-F bond energy. The student incorrectly sketches the potential energy curve for 2 fluorine atoms, shown by the dotted line. 200- 100+ 主一 200 i 600 700 0- 100 300i 400 500 800 -100+ -200- Internuclear Distance (pm) h) Explain the error with the student's sketch for F2(g). Potential Energy (kJ/mol)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Could you please answer parts g and h please? Thank you, I would really appreciate it!
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