An unknown gas, D, reacts with fluorine gas to form the compound DF4(g), as represented by the following equation: D(g)+2 F2(g)→DF4(g). A series of experimental trials were performed at 600° to determine the rate law expression for the reaction. Data from the trials are shown below. Initial PD (torr) Initial PF2 (torr) Initial Rate of Appearance of DF4(g) (torr/min) Trial 1 3000 3000 2.50x10-2 Trial 2 Trial 3 6000 3000 5.0x10-2 3000 6000 10.0x10-2 Fluorine can also react with another gas, E(g), according to the following equation: E(g)+2 F2(g)>EF4(g) AHo=-150 kJ/molx0 g) The student claims that the D-F bond energy is less than the E-F bond energy. Do you agree or disagree? Justify your answer. While investigating the properties of other diatomic molecules, the student finds the following diagram, which shows the potential energy of two iodine atoms versus the distance between their nuclei. The student also finds that the l-I bond energy is slightly less than the F-F bond energy. The student incorrectly sketches the potential energy curve for 2 fluorine atoms, shown by the dotted line. 200- 100+ 主一 200 i 600 700 0- 100 300i 400 500 800 -100+ -200- Internuclear Distance (pm) h) Explain the error with the student's sketch for F2(g). Potential Energy (kJ/mol)

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An unknown gas, D, reacts with fluorine gas to form the compound DF4(g), as represented by the
following equation: D(g)+2 F2(g)>DF4(g). A series of experimental trials were performed at 600° to
determine the rate law expression for the reaction. Data from the trials are shown below.
Initial PD (torr)
Initial PF2 (torr)
Initial Rate of
Appearance of DF4(g)
(torr/min)
Trial 1
3000
3000
2.50x10-2
Trial 2
6000
3000
5.0x10-2
Trial 3
3000
6000
10.0x10-2
Fluorine can also react with another gas, E(g), according to the following equation:
E(g)+2 F2(g)>EF4(g) AHo=-150 kJ/malxn
g) The student claims that the D-F bond energy is less than the E-F bond energy. Do you agree or
disagree? Justify your answer.
While investigating the properties of other diatomic molecules, the student finds the following diagram,
which shows the potential energy of two iodine atoms versus the distance between their nuclei. The
student also finds that the l-I bond energy is slightly less than the F-F bond energy. The
student incorrectly sketches the potential energy curve for 2 fluorine atoms, shown by the dotted line.
200-
100+
主一
200 i
600 700
0-
100
300i 400 500
800
-100+
-200-
Internuclear Distance (pm)
h) Explain the eror with the student's sketch for F2(g).
Potential Energy (kJ/mol)
Transcribed Image Text:An unknown gas, D, reacts with fluorine gas to form the compound DF4(g), as represented by the following equation: D(g)+2 F2(g)>DF4(g). A series of experimental trials were performed at 600° to determine the rate law expression for the reaction. Data from the trials are shown below. Initial PD (torr) Initial PF2 (torr) Initial Rate of Appearance of DF4(g) (torr/min) Trial 1 3000 3000 2.50x10-2 Trial 2 6000 3000 5.0x10-2 Trial 3 3000 6000 10.0x10-2 Fluorine can also react with another gas, E(g), according to the following equation: E(g)+2 F2(g)>EF4(g) AHo=-150 kJ/malxn g) The student claims that the D-F bond energy is less than the E-F bond energy. Do you agree or disagree? Justify your answer. While investigating the properties of other diatomic molecules, the student finds the following diagram, which shows the potential energy of two iodine atoms versus the distance between their nuclei. The student also finds that the l-I bond energy is slightly less than the F-F bond energy. The student incorrectly sketches the potential energy curve for 2 fluorine atoms, shown by the dotted line. 200- 100+ 主一 200 i 600 700 0- 100 300i 400 500 800 -100+ -200- Internuclear Distance (pm) h) Explain the eror with the student's sketch for F2(g). Potential Energy (kJ/mol)
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