An octahedral complex, MA,B2C2 (A, B, C are all monodentate ligands), has a total of 6 stereoisomers. Considering the point groups for each of these isomers, it can be concluded that none of these isomers has the following point group. C2v C1 D2h

An octahedral complex, MA,B2C2 (A, B, C are all monodentate ligands), has a total of 6 stereoisomers. Considering the point groups for each of these isomers, it can be concluded that none of these isomers has the following point group. C2v C1 D2h

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the…

Q: What are the symmetries of the SALCS for sigma bonding in a sawhorse-shaped (disphenoidal)…

A: The symmetries of the SALCS (symmetry adapted linear combinations) for sigma bonding in a…

Q: Determine the d electron configuration of [OsCl6]3-complex.

Q: Draw the electron first excited state electronic diagram of a weak field d7 octahedral…

A: We have to draw the electron first excited state electronic diagram of a weak field d7 octahedral…

Q: b. [Fe(en)Cl₂I₂]² where en = ethylenediamine CN= number of d-electrons = What is the spin-only…

A: The given compound is [Fe(en)Cl2I2]2- where en = ethylene diamine. Coordination compounds are the…

Q: Square planar complexes are often asso with:

A: Square planar complexes are dsp2 hybridised .

Q: The_isomer of [Fe(NH3)3CI3] has C2y symmetry. mer fac

A: Welcome to bartleby!

Q: Determine the symmetry representations of CO stretching vibrations of a Mn(CO)5Br complex, which has…

A: Symmetry representation of CO stretching vibrations of Mn(CO)5Br complex, has a pseudo octahedral…

Q: What point group is produced if an octahedral (Oh) complex is distorted by stretching two trans M-L…

A: The point group of an octahedral complex is Oh, which stands for "Oh" in Schönflies notation. The…

Q: The number of spin allowed electronic transition states for the complex [Ni(en), ]* 2 3 O 1 are

A: The objective of the question is to determine the number of spin allowed electronic transition…

Q: On the diagram, fill in the electrons for [Cr(NH3)6]2+, draw an arrow 2.2 ( indicating the…

Q: Coordination compounds of formula MA4 might be square planar or tetrahedral. How many isomers would…

A: This can be explained by Valance Bond Theory of coordination compound.

Q: Ni(PPh3)Cl2 is a mixture of two complexes. Draw the populated ground state split d orbital diagram…

Q: Work out the stoichiometries and structures of the neutral complexes, chromium carbonyl, rhenium…

Q: draw the appropriate symmetry-adapted linear combinations and the molecular orbital diagram for o…

Q: Write the state of hybridization, shape and IUPAC name of the complex [C0F6]3-. (Atomic no. of Co =…

A: Co-ordination compounds are formed when the metal ion is bonded to the ligand which donates its…

Q: The symmetry of the metal d-orbitals that involve in sigma bond formation in octahedral complex…

A: Thank you.

Q: Point Group please explain mer-[Fe(terpy)2]2+ (Mes)Mo(CO)3

Q: Two coordination sphere isomers for MnCl3(CN)3

Q: Why is the energy of the dxz and dyz orbitals in a square-planar complex lower thanthat of the dxy…

A: The "square planar geometry" contains 4 ligands attached with 1 "central metal atom". In this…

Q: 3. Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the…

Q: Find SALCs and construct the MO diagram for a transition metal complex with octahedral symmetry.

Q: Calculate the gas phase or free ion term for a d8 transition metal ion and the ground and excited…

Q: Ligand Field Stabilization Energy (LFSE) value (units of Δo) for:

Q: Part A Arrange the complexes in order of decreasing stability. Rank from most stable to least…

A: Chelation ligandsChelation ligands are ligands having several donor sites that may interact with…

Q: Carbon monoxide is a good ligand and is toxic. Why is the isoelectronic N2molecule not toxic?

A: Isoelectronic means same number of electrons. Total electrons in CO is 14 (6+8) Total electrons in…

Concept explainers

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.

Question

An octahedral complex, MA,B,C2 (A, B, C are all monodentate ligands), has a total of 6 stereoisomers. Considering the point
groups for each of these isomers, it can be concluded that none of these isomers has the following point group.
C2v
C1
D2h
Which cation is mostly likely to form a complex with SCN' b
Cs

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Consider the complex square planar complex NiL4, where Ni2+ (d) is the central ion. Draw the system showing axes and answer the following: 1) Show how Group theory to find symmetries for Sigma bonding 2) Show how Group theory can find symmetries for in- plane and out of plane Pi bonds 3) Use the Projection Operator Method to find out LGOs (all of them) used in the out of plane Pi bonding
1) ClassAu as dicimagnetic cr paramagnetic: 3+ ACinisolated. gas-phaoeCr" lon. ahgh-spincdahedral Crt Complex alawspin oclanerdral CoComper
INORGANIC CHEMISTRY
The symmetry of the metal d-orbitals that involve in sigma bond formation in octahedral complex compounds are 0128 eg eg * 128
The only spin magnetic moment of the central metal in the complex Na3[Mn(CN)6] is-HB. The result must be given with three significant figures (for example 7.34) I
Which dn electron configurations are expected to undergo a Jahn–Teller distortion in a tetrahedral coordination compound? Explain your answer.
What is the most likely mechanism for ligand substitution in square-planar complexes? Group of answer choices association dissociation A wide variety of mechanisms are observed. Chemists have not determined one to take place in most cases. reductive elimination
Given the Tanabe-Sugano diagram below for a d7 complex. Which of the following corresponds to the ground state if the ligand is a strong field ligand? A. 4T1gB.4A2gC.2EgD. 2T1g
1. Using the MO scheme provided below, calculate the bond order for the ligand-metal bonds in a ML6 complex where M=Co2+ and NH3: Recall that independent of the ligand, the eg orbitals that are 10Dq above the t2g orbitals are always o*. M ML6 6L O* 4p d,?.? d,? 2 х - у 4s 3d dy dyz dyz sp3 Op Os
what's the point group of an octahedron with one blue face, the others yellow
Systemic name of the coordination compound (Pt(NH3)2(H20)2(CH3CO2)2][CuBr4]