An electron is confined to a three-dimensional infinite cubic well with side length L = 0.200 nm. The ground state is non-degenerate, while the first excited state is 3-fold degenerate. What is the energy of the lowest energy non-degenerate excited state?
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- 3. Particle in a 2D Box. A quantum mechanical particle is confined in side a square 2D box, with side length L. Inside the box V=0 and outside the box V=infinity. Let the wave function to be (x,y). (a) write down the Schrodinger equation of (x,y). (b) Use the separation of variable method solve (x,y) (let the quantum numbers to be nx and ny.) (c) What is the energy for the state (nx, ny)? (d) What is the probability density p(x,y) for the state nx=3 and ny=3? Sketch this p(x,y) in a square.Chapter 39, Problem 009 Suppose that an electron trapped in a one-dimensional infinite well of width 144 pm is excited from its first excited state to the state with n 9. (a) What energy must be transferred to the electron for this quantum jump? The electron then de- excites back to its ground state by emitting light. In the various possible ways it can do this, what are the (b) shortest, (c) second shortest, (d) longest, and (e) second longest wavelengths that can be emitted? (a) Number Units (b) Number Units (c) Number Units (d) Number Units (e) Number UnitsAn electron is trapped inside a 1.00 nm potential well. Find the wavelength of the photons when the electron makes a transition from n =4 to n= 1.
- Consider a particle in a 2-D box having Lx = 10 nm and Ly = 10 nm. a) Make a surface plot of all the wave functions for the first and second energy levels. b) What is the degeneracy of the second energy level? Compare and contrast the wave functions of the second energy level. c) How does the number of nodes in the x-coordinate change as n increases? How does the number of nodes in the y-coordinate change as n, increases? d) Explain whether or not those same states would be degenerate if Lx = 10 nm and Ly = 15 nm.a 4. 00, -Vo, V(z) = 16a 0, Use the WKB approximation to determine the minimum value that V must have in order for this potential to allow for a bound state.The figures below show the wave function describing two different states of a particle in an infinite square well. The number of nodes (within the well, but excluding the walls) in each wave function is related to the quantum number associated with the state it represents: Wave function A number of nodes = n-1 Wave function B M Determine the wavelength of the light absorbed by the particle in being excited from the state described by the wave function labelled A to the state described by the wave function labelled B. The distance between the two walls is 1.00 × 10-10 m and the mass of the particle is 1.82 × 10-30 kg. Enter the value of the wavelength in the empty box below. Your answer should be specified to an appropriate number of significant figures. wavelength = nm.