Ammonium hydrogen sulfide decomposes according to the following reaction: NH,HS(s)<>H,S(g) + NH3(g)

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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Ammonium hydrogen sulfide decomposes according to the following
reaction:
NH,HS(s)<>H,S(g) + NH;(g)
a) 1 g NH4HS and the ammonia from a 500 cm3 container, which is at 0.530 atm and
250C, are introduced into a closed 2-liter container. Calculate the partial pressure of
hydrogen sulfide at 2500C.
b) For the decomposition of ammonium hydrogen sulfide to be 10%, calculate the
amount of ammonia that must be subtracted or added to the mixture.
Data: ArH° =
92,72 kJ/mol A,S° = 159,58 J/mol K
Besult; a) 0,242 atm; b)0.124 mol
Transcribed Image Text:Ammonium hydrogen sulfide decomposes according to the following reaction: NH,HS(s)<>H,S(g) + NH;(g) a) 1 g NH4HS and the ammonia from a 500 cm3 container, which is at 0.530 atm and 250C, are introduced into a closed 2-liter container. Calculate the partial pressure of hydrogen sulfide at 2500C. b) For the decomposition of ammonium hydrogen sulfide to be 10%, calculate the amount of ammonia that must be subtracted or added to the mixture. Data: ArH° = 92,72 kJ/mol A,S° = 159,58 J/mol K Besult; a) 0,242 atm; b)0.124 mol
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