always on op be a fixed point If fermion elec- ground state? es of the whole ) (b) Suppose If boson. (It is particles are s imagining a he degenera- What would apart. Use this semiclassical model to estimate the potential energy of the two electrons. Combine this with your answer to part (a) to estimate the total energy of the He atom. Compare with the observed ice ag (See the 10.32 (a) Fin and copp cover. ( those in value of -79.0 eV. (Note: since it close to 10.20 . (a) If the electron had spin s = changed in every other respect), how many different orientations would its spin have? (b) Sketch energy- (but was un- almost were some- cupied in the ground states of 4Be and C if the electron had s = one ele they might erent num- arts of this 10.33 Bec 21 smoot SECTION 10.7 (The Remaining Elements) -10.21 Use the energy-level diagram of Fig. 10.9 to write down the electron configurations of 30Zn, 35Br, saXe, 85At, 87F.. catistics" of ticles. (See ic tab eleme (This Few sever dium 10.22 Use the energy-level diagram of Fig. 10.9 to find the electron configurations of 20C , 23 V, 32GE, 53l, 88R.. ener Fig. 10.7, one tate of 12 322 Chapter 10 Multielectron Atoms; the Pauli Principle and Periodic Table FIGURE 10.9 5f 32 14 9. 7p 6d 10 Schematic diagram showing the order in which levels are occupied 7th shell He 7s 2. Z 86 as one considers atoms with 20 4f 32 14 9. 5d successively higher Z. This is not the energy-level diagram for any one atom; it just gives the order in which levels are occupied as Z increases. The shaded rectangles indicate the groupings of nearby levels into energy shells. The figure to the right of each level or shell gives the number of electrons that can be accommodated; the figures on the far right are the atomic numbers Z of the closed-shell 6th 6s бp 10 15 - 54 10 18 10 5th 58 Sp --36 9- 4p 18 10 3d 4th 4s -18 9- Зр 3rd 3s 0.3- atoms. Note that some levels are 0.2 too close to be ordered unambiguously; for example, 5d is partially occupied before 4f, but 4f is completely filled before 5d. The exact sequence of occupancy can be found from the electron - 10 9- 2p 2nd 8. 2s 0.1 2. 1st 1s configurations shown inside the back cover. After 19K comes calcium (20Ca), whose 4s level is full. Then with scandiun (21SC), the 3d level begins to fill. Since any d level can hold 10 electrons filling of the 3d level talcon 2.

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How do I make the configurations to problem 10.21?

always on op
be a fixed point
If fermion elec-
ground state?
es of the whole
) (b) Suppose
If boson. (It is
particles are
s imagining a
he degenera-
What would
apart. Use this semiclassical model to estimate the
potential energy of the two electrons. Combine this
with your answer to part (a) to estimate the total
energy of the He atom. Compare with the observed
ice ag
(See the
10.32 (a) Fin
and copp
cover. (
those in
value of -79.0 eV.
(Note:
since it
close to
10.20 . (a) If the electron had spin s =
changed in every other respect), how many different
orientations would its spin have? (b) Sketch energy-
(but was un-
almost
were some-
cupied in the ground states of 4Be and C if the
electron had s =
one ele
they might
erent num-
arts of this
10.33 Bec
21
smoot
SECTION 10.7 (The Remaining Elements)
-10.21 Use the energy-level diagram of Fig. 10.9 to write
down the electron configurations of 30Zn, 35Br, saXe,
85At, 87F..
catistics" of
ticles. (See
ic tab
eleme
(This
Few
sever
dium
10.22 Use the energy-level diagram of Fig. 10.9 to find the
electron configurations of 20C , 23 V, 32GE, 53l, 88R..
ener
Fig. 10.7,
one
tate of
12
Transcribed Image Text:always on op be a fixed point If fermion elec- ground state? es of the whole ) (b) Suppose If boson. (It is particles are s imagining a he degenera- What would apart. Use this semiclassical model to estimate the potential energy of the two electrons. Combine this with your answer to part (a) to estimate the total energy of the He atom. Compare with the observed ice ag (See the 10.32 (a) Fin and copp cover. ( those in value of -79.0 eV. (Note: since it close to 10.20 . (a) If the electron had spin s = changed in every other respect), how many different orientations would its spin have? (b) Sketch energy- (but was un- almost were some- cupied in the ground states of 4Be and C if the electron had s = one ele they might erent num- arts of this 10.33 Bec 21 smoot SECTION 10.7 (The Remaining Elements) -10.21 Use the energy-level diagram of Fig. 10.9 to write down the electron configurations of 30Zn, 35Br, saXe, 85At, 87F.. catistics" of ticles. (See ic tab eleme (This Few sever dium 10.22 Use the energy-level diagram of Fig. 10.9 to find the electron configurations of 20C , 23 V, 32GE, 53l, 88R.. ener Fig. 10.7, one tate of 12
322 Chapter 10 Multielectron Atoms; the Pauli Principle and Periodic Table
FIGURE 10.9
5f
32
14
9.
7p
6d
10
Schematic diagram showing the
order in which levels are occupied
7th shell
He
7s
2.
Z 86
as one considers atoms with
20
4f
32
14
9.
5d
successively higher Z. This is not
the energy-level diagram for any
one atom; it just gives the order in
which levels are occupied as Z
increases. The shaded rectangles
indicate the groupings of nearby
levels into energy shells. The figure
to the right of each level or shell
gives the number of electrons that
can be accommodated; the figures
on the far right are the atomic
numbers Z of the closed-shell
6th
6s
бp
10
15
- 54
10
18
10
5th
58
Sp
--36
9-
4p
18
10
3d
4th
4s
-18
9-
Зр
3rd
3s
0.3-
atoms. Note that some levels are
0.2
too close to be ordered
unambiguously; for example, 5d is
partially occupied before 4f, but 4f
is completely filled before 5d. The
exact sequence of occupancy can
be found from the electron
- 10
9-
2p
2nd
8.
2s
0.1
2.
1st
1s
configurations shown inside the
back cover.
After 19K comes calcium (20Ca), whose 4s level is full. Then with scandiun
(21SC), the 3d level begins to fill. Since any d level can hold 10 electrons
filling of the 3d level talcon
2.
Transcribed Image Text:322 Chapter 10 Multielectron Atoms; the Pauli Principle and Periodic Table FIGURE 10.9 5f 32 14 9. 7p 6d 10 Schematic diagram showing the order in which levels are occupied 7th shell He 7s 2. Z 86 as one considers atoms with 20 4f 32 14 9. 5d successively higher Z. This is not the energy-level diagram for any one atom; it just gives the order in which levels are occupied as Z increases. The shaded rectangles indicate the groupings of nearby levels into energy shells. The figure to the right of each level or shell gives the number of electrons that can be accommodated; the figures on the far right are the atomic numbers Z of the closed-shell 6th 6s бp 10 15 - 54 10 18 10 5th 58 Sp --36 9- 4p 18 10 3d 4th 4s -18 9- Зр 3rd 3s 0.3- atoms. Note that some levels are 0.2 too close to be ordered unambiguously; for example, 5d is partially occupied before 4f, but 4f is completely filled before 5d. The exact sequence of occupancy can be found from the electron - 10 9- 2p 2nd 8. 2s 0.1 2. 1st 1s configurations shown inside the back cover. After 19K comes calcium (20Ca), whose 4s level is full. Then with scandiun (21SC), the 3d level begins to fill. Since any d level can hold 10 electrons filling of the 3d level talcon 2.
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