Although we learned in Section 5.4 that uncharged nitrogen atoms generally cannot be chiral centers (due to nitrogen inversion), an exception is Tröger's base. Tröger's base has two enantiomers that can be separated from each other. They are different in their configurations at
Although we learned in Section 5.4 that uncharged nitrogen atoms generally cannot be chiral centers (due to nitrogen inversion), an exception is Tröger's base. Tröger's base has two enantiomers that can be separated from each other. They are different in their configurations at
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Although we learned in Section 5.4 that uncharged nitrogen atoms generally cannot be chiral centers (due to nitrogen inversion), an exception is Tröger's base. Tröger's base has two enantiomers that can be separated from each other. They are different in their configurations at the N atoms. One enantiomer is shown on the right, viewed from two different perspectives. (a) Draw the second enantiomer of Tröger's base. (b) Explain why the two enantiomers do not interconvert. Tröger's base
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