although we associate Pz 2. Now we will move on to diatomic molecules. In atoms all p-orbitals are equivalent with m/= 0, and px py with m/= ±1. In diatomic molecules these orbitals are in fact separated, with pz associated with o orbitals along the internuclear axis and px py associated with л orbitals (m/= ±1). In determining electron configurations we do indeed separate them: N₂ (KK¹ 0₂²). and O2 (KKogu ng *2). 4 a. Two excited states of N₂ are associated with Tu transitions. Tg and og → ou* i. Draw the MO energy level scheme (p-orbitals only) for the N₂ ground state and for these two excited states. ii. Obtain the term symbols for the two excited states and order them according to Hund's rules. iii. Write the wave functions for each of the terms obtained in ii) above. iv. Pick one wave function from each excited state and show it obeys the Pauli Principle.

although we associate Pz 2. Now we will move on to diatomic molecules. In atoms all p-orbitals are equivalent with m/= 0, and px py with m/= ±1. In diatomic molecules these orbitals are in fact separated, with pz associated with o orbitals along the internuclear axis and px py associated with л orbitals (m/= ±1). In determining electron configurations we do indeed separate them: N₂ (KK¹ 0₂²). and O2 (KKogu ng 2). 4 a. Two excited states of N₂ are associated with Tu transitions. Tg and og → ou i. Draw the MO energy level scheme (p-orbitals only) for the N₂ ground state and for these two excited states. ii. Obtain the term symbols for the two excited states and order them according to Hund's rules. iii. Write the wave functions for each of the terms obtained in ii) above. iv. Pick one wave function from each excited state and show it obeys the Pauli Principle.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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