Although carbon and oxygen have significantly different electronegativities, CO2 cannot easily be separated from air by applying a voltage in the smokestack of the power plant where it is generated. How does the geometry of carbon dioxide account for this observation?

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One of the “grand challenges” for engineering recently identified by the U.S. National Academy of Engineering is the capture of carbon dioxide produced by the burning of fossil fuels. Although carbon and oxygen have significantly different electronegativities, CO2 cannot easily be separated from air by applying a voltage in the smokestack of the power plant where it is generated. How does the geometry of carbon dioxide account for this observation?
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